This book highlights the theories and research progress in gaseous detonation research, and proposes a universal framework theory that overcomes the current research limitations. Gaseous detonation is an extremely fast type of combustion that propagates at supersonic speed in premixed combustible gas. Being self-sustaining and self-organizing with the unique nature of pressure gaining, gaseous detonation and its gas dynamics has been an interdisciplinary frontier for decades. The research of detonation enjoyed its early success from the development of the CJ theory and ZND modeling, but phenomenon is far from being understood quantitatively, and the development of theories to predict the three-dimensional cellular structure remains a formidable task, being essentially a problem in high-speed compressible reacting flow. This theory proposed by the authors’ research group breaks down the limitation of the one-dimensional steady flow hypothesis of the early theories, successfully correlating the propagation and initiation processes of gaseous detonation, and realizing the unified expression of the three-dimensional structure of cell detonation. The book and the proposed open framework is of high value for researchers in conventional applications such as coal mine explosions and chemical plant accidents, and state-of-the-art research fields such as supernova explosion, new aerospace propulsion engines, and detonation-driven hypersonic testing facilities. It is also a driving force for future research of detonation.
This Brief provides an up-to-date overview of smart surfactants and describes a broad spectrum of triggers that induce the formation of wormlike micelles or reversibly tune the morphology of surfactant aggregates from wormlike micelles to another state, or vice versa. Combining the fields of chemistry, physics, polymer science, and nanotechnology, its primary focus is on the design, formulation, and processing of intelligent viscoelastic surfactant solutions, covering the scientific principles governing responsiveness to one or more particular triggers, down to the end-use-driven functions. The first chapter explains why and how surfactants self-assemble into viscoelastic wormlike micellar solutions reminiscent of polymer solutions, while the following chapters show how the response to a given trigger translates into macroscopic rheological changes, including temperature, light, pH, CO2, redox, hydrocarbon, etc. The last chapter demonstrates the applications of these viscoelastic assemblies in oil and gas production, drag reduction, biomaterials, cleaning processes, electrorheological and photorheological fluids. Comments and perspectives are provided at the end to conclude this Brief. This Brief is aimed at chemists, physicists, chemical engineers and nano-scientists who are involved in self-assemblies and applications of surfactants, as well as graduates in physical chemistry. Yujun Feng, Ph.D., is a professor at the State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, Sichuan Province, P. R. China. Zonglin Chu, Ph.D., is a post-doctoral fellow working at the Physical Chemistry Institute, University of Zürich, Switzerland. Cécile A. Dreiss, Ph.D., is a senior lecturer at the Institute of Pharmaceutical Science, King’s College London, UK.
This book highlights the theories and research progress in gaseous detonation research, and proposes a universal framework theory that overcomes the current research limitations. Gaseous detonation is an extremely fast type of combustion that propagates at supersonic speed in premixed combustible gas. Being self-sustaining and self-organizing with the unique nature of pressure gaining, gaseous detonation and its gas dynamics has been an interdisciplinary frontier for decades. The research of detonation enjoyed its early success from the development of the CJ theory and ZND modeling, but phenomenon is far from being understood quantitatively, and the development of theories to predict the three-dimensional cellular structure remains a formidable task, being essentially a problem in high-speed compressible reacting flow. This theory proposed by the authors’ research group breaks down the limitation of the one-dimensional steady flow hypothesis of the early theories, successfully correlating the propagation and initiation processes of gaseous detonation, and realizing the unified expression of the three-dimensional structure of cell detonation. The book and the proposed open framework is of high value for researchers in conventional applications such as coal mine explosions and chemical plant accidents, and state-of-the-art research fields such as supernova explosion, new aerospace propulsion engines, and detonation-driven hypersonic testing facilities. It is also a driving force for future research of detonation.
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