Why are atoms so small?' asks 'naive physicist' in Erwin Schrodinger's book 'What is Life? The Physical Aspect of the Living Cell'. 'The question is wrong' answers the author, 'the actual problem is why we are built of such an enormous number of these particles'. The idea that everything is built of atoms is quite an old one. It seems that l Democritus himself borrowed it from some obscure Phoenician source . The arguments for the existence of small indivisible units of matter were quite simple. 2 According to Lucretius observable matter would disappear by 'wear and tear' (the world exists for a sufficiently long, if not infinitely long time) unless there are some units which cannot be further split into parts. th However, in the middle of the 19 century any reference to the atomic structure of matter was considered among European physicists as a sign of extremely bad taste and provinciality. The hypothesis of the ancient Greeks (for Lucretius had translated Epicurean philosophy into Latin hexameters) was at that time seen as bringing nothing positive to exact science. The properties of gaseous, liquid and solid bodies, as well as the behaviour of heat and energy, were successfully described by the rapidly developing science of thermodynamics.
This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes.Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades.
The book is intended to help under- and postgraduate students and young scientists in the correct application of NMR to the solution of physico-chemical problems concerning the study of equilibria in solution. The first part of the book (Chapters 1-3) is a trivium, but should enable a student to design and conduct simple physico-chemical NMR experiments. The following chapters give illustrative material on the physico-chemical applications of NMR of increasing complexity. These chapters include the problem of determination of equilibrium and rate constants in solution, the study of paramagnetism using NMR, the application of Dynamic NMR techniques and relaxation measurements. A multipurpose nonlinear regression program is supplied (on disc for PC) and is referred to throughout the book.
Der Grundkurs Theoretische Physik deckt in sieben Bänden alle für Diplom- und Bachelor/Master-Studiengänge maßgeblichen Gebiete ab. Jeder Band vermittelt das im jeweiligen Semester nötige theoretisch-physikalische Rüstzeug. Übungsaufgaben mit ausführlichen Lösungen dienen der Vertiefung des Stoffs. Band 1 behandelt die klassische Mechanik. Vorausgesetzt wird nur die übliche Schulmathematik, andere mathematische Hilfsmittel werden zu Beginn ausführlich erläutert. Die zweifarbig gestaltete Neuauflage wurde grundlegend überarbeitet und ergänzt.
This textbook describes Earth's plasma environment from single particle motion in electromagnetic fields, with applications to Earth's magnetosphere, up to plasma wave generation and wave-particle interaction. The origin and effects of collisions and conductivities are discussed in detail, as is the formation of the ionosphere, the origin of magnetospheric convection and magnetospheric dynamics in solar wind-magnetosphere coupling, the evolution of magnetospheric storms, auroral substorms, and auroral phenomena of various kinds.The second half of the book presents the theoretical foundation of space plasma physics, from kinetic theory of plasma through the formation of moment equations and derivation of magnetohydrodynamic theory of plasmas. The validity of this theory is elucidated, and two-fluid theory is presented in more detail. This is followed by a brief analysis of fluid boundaries, with Earth's magnetopause and bow shock as examples. The main emphasis is on the presentation of fluid and kinetic wave theory, deriving the relevant wave modes in a high temperature space plasma. Plasma instability is the most important topic in all applications and is discussed separately, including a section on thermal fluctuations. These theories are applied to the most interesting problems in space plasma physics, collisionless reconnection and collisionless shock waves with references provided. The Appendix includes the most recent developments in the theory of statistical particle distributions in space plasma, the Kappa distribution, etc, also including a section on space plasma turbulence and emphasizing on new observational developments with a dimensional derivation of the Kolmogorov spectrum, which might be instructive for the student who may worry about its origin.The book ends with a section on space climatology, space meteorology and space weather, a new application field in space plasma physics that is of vital interest when considering the possible hazards to civilization from space.
Why are atoms so small?' asks 'naive physicist' in Erwin Schrodinger's book 'What is Life? The Physical Aspect of the Living Cell'. 'The question is wrong' answers the author, 'the actual problem is why we are built of such an enormous number of these particles'. The idea that everything is built of atoms is quite an old one. It seems that l Democritus himself borrowed it from some obscure Phoenician source . The arguments for the existence of small indivisible units of matter were quite simple. 2 According to Lucretius observable matter would disappear by 'wear and tear' (the world exists for a sufficiently long, if not infinitely long time) unless there are some units which cannot be further split into parts. th However, in the middle of the 19 century any reference to the atomic structure of matter was considered among European physicists as a sign of extremely bad taste and provinciality. The hypothesis of the ancient Greeks (for Lucretius had translated Epicurean philosophy into Latin hexameters) was at that time seen as bringing nothing positive to exact science. The properties of gaseous, liquid and solid bodies, as well as the behaviour of heat and energy, were successfully described by the rapidly developing science of thermodynamics.
This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes.Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades.
The book is intended to help under- and postgraduate students and young scientists in the correct application of NMR to the solution of physico-chemical problems concerning the study of equilibria in solution. The first part of the book (Chapters 1-3) is a trivium, but should enable a student to design and conduct simple physico-chemical NMR experiments. The following chapters give illustrative material on the physico-chemical applications of NMR of increasing complexity. These chapters include the problem of determination of equilibrium and rate constants in solution, the study of paramagnetism using NMR, the application of Dynamic NMR techniques and relaxation measurements. A multipurpose nonlinear regression program is supplied (on disc for PC) and is referred to throughout the book.
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