This book subtitled The Chemistry of Initiation of Non-Ringed Compounds/Monomers is the second Volume [Vol. (II)] of the book titled The New Frontiers in Sciences, Engineering and the Arts. For a compound to undergo Initiation, it must be such that has what is called Activation center(s) wherein there are three kinds of many types. When such compounds are activated, they can be made to undergo either polymeric or chemical reactions. When made to undergo polymeric reactions, the compounds are said to be Addition monomers. It is only when the Initiation Step is favoured by the monomer using an Initiator, that the Propagation Step begins, just as when a child is born into our world, the child begins to grow. If the Initiation Step is not favoured, due to presence of what are called Transfer Species, then chemical reactions take place to give non-polymeric products under Equilibrium mechanism conditions. There are different kinds and types of Transfer Species. They are so important to the point where they indeed embrace the first law in Chemistry, that which has been called The law of Conservation of transfer of transfer species, almost analogous to the Conservation laws in Engineering. Based on this law, so many new concepts too countless to list were identified. How some compounds/monomers rearrange to give other compounds/monomers via different kinds of phenomena all new to Present-day Science, have been identified. So also, are the concepts of Resonance Stabilization which was thought to take place chargedly, something very impossible. There are also many monomers which Present-day Science activate chargedly, things all found to be impossible. Indeed, as has been said, all chemical reactions take place only radically, while only some polymeric reactions take place chargedly, in view of the types of mechanisms involved. Different families of compounds/monomers with activation centers, both known and unknown, olefinic and non-olefinic were considered, providing their chemical behaviours under different operating conditions, based on the New Science. Unlike what is known in Present-day Science, there are Males (called Electrophiles) and Females (called Nucleophiles) compounds/monomers; indeed, more of Females than Males. While Males carry at least two different types of Activation centers cumulatively or conjugatedly placed, Females carry one, two or more same types of activation centers. How these monomers all coming from different family trees favour the routes favoured by them have been shown, even to the point where some which could not be polymerized by Present-day Science, can now be polymerized. For the first time, one has shown what the Hydrocarbon family tree looks like. In view of the absence of hetero atoms in the tree, there are no Males for those that carry Activation centers. For the first time, Azo compounds including hydrocarbons have been renamed and reclassified. How they decompose when catalyzed and non-catalyzed, have begun to be shown. They are important, because from there one began to distinguish between surface and laboratory or industrial chemistry. For the first time, one showed how membranes can be obtained from chitins. So also, one has shown how the oxidation of ortho-xylene which Present-day Science thought was also combustion to give phthalic anhydride using vanadium pentoxide takes place. From all indications, a new science has emerged.
Volume III titled The Chemistry of Initiation of Ringed, Ring-Forming and Polymeric Monomers/Compounds completes the initiation of compounds for chemical and homopolymeric reactions (section D). The volume is a section that contains six chapters and is indeed a continuation of Volume II. However, in view of the size of this volume (section D), it has been divided into two books: Volume III-A and Volume III-B. Volume III-B, which contains part II and part III, is a continuation of Volume III-A, which is part I.
Ringed compounds are very unique in Nature, because the human skeletal foundation as will be seen in Vol VI), from the Head to the Toes are made of ringed compounds (the steroids). It is from the Chemistry of ringed compounds, one can see the Physics of Springs with respect to many concepts such as Strain Energies. There are rings which cannot be opened and there are others which can readily be opened. How rings are formed and opened are unknown to Chemists universally; but they think they know. The characters of rings, the conditions favoring their openings, expansions and reduction in size and formations, the manners by which rings are opened or closed, etc. have been clearly explained. Having covered virtually every type of rings, all the different types of resonance stabilization and molecular rearrangement phenomena and other phenomena present in these systems have begun to be fully identified. For the first time for example, how meta, ortho- and para-substitutions take place in benzene rings, 2-,5- positions or 3-,4- positions substitutions take place in pyrrole, furan and thiophene rings etc. have been clearly explained based on the types of resonance stabilization phenomena favored by them. After every chapter beginning from Vol (II), Rules of Chemistry were stated relating not only to the materials in that chapter, but also to the past and in fact the future. In the last chapter of Vol (III)B, all rules coming from The beginning of a New Dawn for Humanity and also from Vol (I), were stated. These rules are not just ordinary rules, but an embracement of how Nature operates. Amongst ringed compounds/monomers, there are Males (called Electrophiles) and Females (called Nucleophiles), based on the types of Activation centers carried by them Why some favor being used as monomers and others do not, have been clearly explained. Nucleophilic, electrophilic, radical-pushing and radical-pulling capacities of the compounds and their substituted groups (new) have been provided. Before understanding this Volume, Volumes (I) and (II) as well as The Beginning of a New Dawn for Humanity, must be read. This Volume will find most useful applications to the medical scientists, biochemists, chemical and other related disciplines, where little or nothing is indeed known about ringed compounds.
This book subtitled The Chemistry of Initiation of Non-Ringed Compounds/Monomers is the second Volume [Vol. (II)] of the book titled The New Frontiers in Sciences, Engineering and the Arts. For a compound to undergo Initiation, it must be such that has what is called Activation center(s) wherein there are three kinds of many types. When such compounds are activated, they can be made to undergo either polymeric or chemical reactions. When made to undergo polymeric reactions, the compounds are said to be Addition monomers. It is only when the Initiation Step is favoured by the monomer using an Initiator, that the Propagation Step begins, just as when a child is born into our world, the child begins to grow. If the Initiation Step is not favoured, due to presence of what are called Transfer Species, then chemical reactions take place to give non-polymeric products under Equilibrium mechanism conditions. There are different kinds and types of Transfer Species. They are so important to the point where they indeed embrace the first law in Chemistry, that which has been called The law of Conservation of transfer of transfer species, almost analogous to the Conservation laws in Engineering. Based on this law, so many new concepts too countless to list were identified. How some compounds/monomers rearrange to give other compounds/monomers via different kinds of phenomena all new to Present-day Science, have been identified. So also, are the concepts of Resonance Stabilization which was thought to take place chargedly, something very impossible. There are also many monomers which Present-day Science activate chargedly, things all found to be impossible. Indeed, as has been said, all chemical reactions take place only radically, while only some polymeric reactions take place chargedly, in view of the types of mechanisms involved. Different families of compounds/monomers with activation centers, both known and unknown, olefinic and non-olefinic were considered, providing their chemical behaviours under different operating conditions, based on the New Science. Unlike what is known in Present-day Science, there are Males (called Electrophiles) and Females (called Nucleophiles) compounds/monomers; indeed, more of Females than Males. While Males carry at least two different types of Activation centers cumulatively or conjugatedly placed, Females carry one, two or more same types of activation centers. How these monomers all coming from different family trees favour the routes favoured by them have been shown, even to the point where some which could not be polymerized by Present-day Science, can now be polymerized. For the first time, one has shown what the Hydrocarbon family tree looks like. In view of the absence of hetero atoms in the tree, there are no Males for those that carry Activation centers. For the first time, Azo compounds including hydrocarbons have been renamed and reclassified. How they decompose when catalyzed and non-catalyzed, have begun to be shown. They are important, because from there one began to distinguish between surface and laboratory or industrial chemistry. For the first time, one showed how membranes can be obtained from chitins. So also, one has shown how the oxidation of ortho-xylene which Present-day Science thought was also combustion to give phthalic anhydride using vanadium pentoxide takes place. From all indications, a new science has emerged.
Introduction to New Classifications of Polymeric Systems and New Concepts in Chemistry is the first volume of New Frontiers in Sciences, Engineering and the Arts. It is the first, because of the importance of polymers in our lives and world. With life, steroids, DNAs RNAs, enzymes, most of the food we eat, and more are polymeric in character. Without the polymer industry, the largest industry in the whole worldelectrical and electronic industries, Automobiles industries, kitchen and household industries, packaging industries, oil and gas industries, sound and current industries, and more too countless to listcannot exist both in our physical and natural world, a complex world. The greatest subject area in chemistry is polymer chemistry; for without it, one would not have been able to see what the atom is. It was only in recent years that some great scientists began to see that the electron does not exist outside the nucleus of an atom, but probably inside the nucleus. Indeed, where they exist is still unknown to them. What indeed are outside the nucleus are what some great scientists sometimes call radicals. What these radicals are have remained unknown to humanity. For example, how can radicals add during free-radical or radical polymerizations when they have not been identified just like the ions and charges have with, for example, their males and females. One was able to ask this very deep question based on ones background in polymer chemistry at secondary, bachelors, masters, and PhD levels. Otherwise, others can. Finding solutions to it led to the New Frontiers using universal data abundantly available. With this newly added definition for an atom, one discovered that what all scientists, engineers, medical doctors, and experts in all disciplines have been doing have all been based on the use of universal data, 95 percent of which have wrong interpretationsa complete world of illusions. Is it not shocking to note that all chemists, whether polymeric or not, do not know what a monomer or compound is, or how chemical and polymeric reactions take place. Is it not shocking to note that the electrical and electronic engineers do not know how current and sound flows in some metals and liquids and in space. These and so much more are the origins of the New Frontiers, beginning with this first volume wherein new concepts seen in the first book, The Beginning of a New Dawn for Humanity emerged from.
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