Complexity and Complex Thermoeconomic Systems describes the properties of complexity and complex thermo-economic systems as the consequence of formulations, definitions, tools, solutions and results consistent with the best performance of a system. Applying to complex systems contemporary advanced techniques, such as static optimization, optimal control, and neural networks, this book treats the systems theory as a science of general laws for functional integrities. It also provides a platform for the discussion of various definitions of complexity, complex hierarchical structures, self-organization examples, special references, and historical issues. This book is a valuable reference for scientists, engineers and graduated students in chemical, mechanical, and environmental engineering, as well as those in physics, ecology and biology, helping them better understand the complex thermodynamic systems and enhance their technical skills in research. - Provides a lucid presentation of the dynamical properties of thermoeconomic systems - Includes original graphical material that illustrates the properties of complex systems - Written by a first-class expert in the field of advanced methods in thermodynamics
Despite the vast research on energy optimization and process integration, there has to date been no synthesis linking these together. This book fills the gap, presenting optimization and integration in energy and process engineering. The content is based on the current literature and includes novel approaches developed by the authors. Various thermal and chemical systems (heat and mass exchangers, thermal and water networks, energy converters, recovery units, solar collectors, and separators) are considered. Thermodynamics, kinetics and economics are used to formulate and solve problems with constraints on process rates, equipment size, environmental parameters, and costs. Comprehensive coverage of dynamic optimization of energy conversion systems and separation units is provided along with suitable computational algorithms for deterministic and stochastic optimization approaches based on: nonlinear programming, dynamic programming, variational calculus, Hamilton-Jacobi-Bellman theory, Pontryagin's maximum principles, and special methods of process integration. Integration of heat energy and process water within a total site is shown to be a significant factor reducing production costs, in particular costs of utilities for the chemical industry. This integration involves systematic design and optimization of heat exchangers and water networks (HEN and WN). After presenting basic, insight-based Pinch Technology, systematic, optimization-based sequential and simultaneous approaches to design HEN and WN are described. Special consideration is given to the HEN design problem targeting stage, in view of its importance at various levels of system design. Selected, advanced methods for HEN synthesis and retrofit are presented. For WN design a novel approach based on stochastic optimization is described that accounts for both grassroot and revamp design scenarios. - Presents a unique synthesis of energy optimization and process integration that applies scientific information from thermodynamics, kinetics, and systems theory - Discusses engineering applications including power generation, resource upgrading, radiation conversion and chemical transformation, in static and dynamic systems - Clarifies how to identify thermal and chemical constraints and incorporate them into optimization models and solutions
Complexity and Complex Ecological Systems is an extension of Elsevier's 2021 book Complexity and Complex Chemo-Electric Systems directed toward the analysis and synthesis of diverse ecological processes running in heterogeneous macrosystems. Contemporary advanced techniques such as averaged analysis, food webs approaches, and classical optimization results along with some numerical algorithms are commonly used in ecosystems. This book treats ecological systems as specific functional integrities. In Complexity and Complex Ecological Systems, one can observe how various types of ecological heterogeneities can contribute to flows of living and inanimate parts of the moving pseudo-continuum. This book is a valuable reference for scientists, engineers, and graduate students of environmental, chemical, and biological engineering, helping them better understand complex macroscopic systems and enhance their technical skills in theoretical and practical research. - Covers the basic aspects of modeling, analysis, synthesis, and optimization of ecological systems - Contains theory of selected ecosystems and explanations of how it can be used in applications - Includes original drawings and drafts that illustrate the properties of diverse ecosystems - Written by an expert in advanced methods of biophysics and macroscopic physics
Despite the vast research on energy optimization and process integration, there has to date been no synthesis linking these together. This book fills the gap, presenting optimization and integration in energy and process engineering. The content is based on the current literature and includes novel approaches developed by the authors. Various thermal and chemical systems (heat and mass exchangers, thermal and water networks, energy converters, recovery units, solar collectors, and separators) are considered. Thermodynamics, kinetics and economics are used to formulate and solve problems with constraints on process rates, equipment size, environmental parameters, and costs. Comprehensive coverage of dynamic optimization of energy conversion systems and separation units is provided along with suitable computational algorithms for deterministic and stochastic optimization approaches based on: nonlinear programming, dynamic programming, variational calculus, Hamilton-Jacobi-Bellman theory, Pontryagin's maximum principles, and special methods of process integration. Integration of heat energy and process water within a total site is shown to be a significant factor reducing production costs, in particular costs of utilities for the chemical industry. This integration involves systematic design and optimization of heat exchangers and water networks (HEN and WN). After presenting basic, insight-based Pinch Technology, systematic, optimization-based sequential and simultaneous approaches to design HEN and WN are described. Special consideration is given to the HEN design problem targeting stage, in view of its importance at various levels of system design. Selected, advanced methods for HEN synthesis and retrofit are presented. For WN design a novel approach based on stochastic optimization is described that accounts for both grassroot and revamp design scenarios. - Presents a unique synthesis of energy optimization and process integration that applies scientific information from thermodynamics, kinetics, and systems theory - Discusses engineering applications including power generation, resource upgrading, radiation conversion and chemical transformation, in static and dynamic systems - Clarifies how to identify thermal and chemical constraints and incorporate them into optimization models and solutions
Complexity and Complex Chemo-Electric Systems presents an analysis and synthesis of chemo-electric systems, providing insights on transports in electrolytes, electrode reactions, electrocatalysis, electrochemical membranes, and various aspects of heterogeneous systems and electrochemical engineering. The book describes the properties of complexity and complex chemo-electric systems as the consequence of formulations, definitions, tools, solutions and results that are often consistent with the best performance of the system. The book handles cybernetics, systems theory and advanced contemporary techniques such as optimal control, neural networks and stochastic optimizations (adaptive random search, genetic algorithms, and simulated annealing). A brief part of the book is devoted to issues such as various definitions of complexity, hierarchical structures, self-organization examples, special references, and historical issues. This resource complements Sieniutycz' recently published book, Complexity and Complex Thermodynamic Systems, with its inclusion of complex chemo-electric systems in which complexities, emergent properties and self-organization play essential roles. - Covers the theory and applications of complex chemo-electric systems through modeling, analysis, synthesis and optimization - Provides a clear presentation of the applications of transport theory to electrolyte solutions, heterogeneous electrochemical systems, membranes, electro-kinetic phenomena and interface processes - Includes numerous explanatory graphs and drawings that illustrate the properties and complexities in complex chemo-electric systems - Written by an experienced expert in the field of advanced methods in thermodynamics and related aspects of macroscopic physics
Energy Optimization in Process Systems and Fuel Cells, Third Edition covers the optimization and integration of energy systems, with a particular focus on fuel cell technology. With rising energy prices, imminent energy shortages, and the increasing environmental impacts of energy production, energy optimization and systems integration is critically important. The book applies thermodynamics, kinetics and economics to study the effect of equipment size, environmental parameters, and economic factors on optimal power production and heat integration. Author Stanislaw Sieniutycz, highly recognized for his expertise and teaching, shows how costs can be substantially reduced, particularly in utilities common in the chemical industry. This third edition contains substantial revisions and modifications, with new material on catalytic reactors, sorption systems, sorbent or catalyst regenerators, dryers, and more. - Presents a unified approach to the optimization and integration of energy systems - Includes a large number of examples treating dynamical systems - Provides exposition showing the power of thermodynamics - Contains a large number of maximum power analyses and their extensions
Thermodynamic Approaches in Engineering Systems responds to the need for a synthesizing volume that throws light upon the extensive field of thermodynamics from a chemical engineering perspective that applies basic ideas and key results from the field to chemical engineering problems. This book outlines and interprets the most valuable achievements in applied non-equilibrium thermodynamics obtained within the recent fifty years. It synthesizes nontrivial achievements of thermodynamics in important branches of chemical and biochemical engineering. Readers will gain an update on what has been achieved, what new research problems could be stated, and what kind of further studies should be developed within specialized research. - Presents clearly structured chapters beginning with an introduction, elaboration of the process, and results summarized in a conclusion - Written by a first-class expert in the field of advanced methods in thermodynamics - Provides a synthesis of recent thermodynamic developments in practical systems - Presents very elaborate literature discussions from the past fifty years
Complexity and Complex Chemo-Electric Systems presents an analysis and synthesis of chemo-electric systems, providing insights on transports in electrolytes, electrode reactions, electrocatalysis, electrochemical membranes, and various aspects of heterogeneous systems and electrochemical engineering. The book describes the properties of complexity and complex chemo-electric systems as the consequence of formulations, definitions, tools, solutions and results that are often consistent with the best performance of the system. The book handles cybernetics, systems theory and advanced contemporary techniques such as optimal control, neural networks and stochastic optimizations (adaptive random search, genetic algorithms, and simulated annealing). A brief part of the book is devoted to issues such as various definitions of complexity, hierarchical structures, self-organization examples, special references, and historical issues. This resource complements Sieniutycz' recently published book, Complexity and Complex Thermodynamic Systems, with its inclusion of complex chemo-electric systems in which complexities, emergent properties and self-organization play essential roles. - Covers the theory and applications of complex chemo-electric systems through modeling, analysis, synthesis and optimization - Provides a clear presentation of the applications of transport theory to electrolyte solutions, heterogeneous electrochemical systems, membranes, electro-kinetic phenomena and interface processes - Includes numerous explanatory graphs and drawings that illustrate the properties and complexities in complex chemo-electric systems - Written by an experienced expert in the field of advanced methods in thermodynamics and related aspects of macroscopic physics
Thermodynamic Approaches in Engineering Systems responds to the need for a synthesizing volume that throws light upon the extensive field of thermodynamics from a chemical engineering perspective that applies basic ideas and key results from the field to chemical engineering problems. This book outlines and interprets the most valuable achievements in applied non-equilibrium thermodynamics obtained within the recent fifty years. It synthesizes nontrivial achievements of thermodynamics in important branches of chemical and biochemical engineering. Readers will gain an update on what has been achieved, what new research problems could be stated, and what kind of further studies should be developed within specialized research. - Presents clearly structured chapters beginning with an introduction, elaboration of the process, and results summarized in a conclusion - Written by a first-class expert in the field of advanced methods in thermodynamics - Provides a synthesis of recent thermodynamic developments in practical systems - Presents very elaborate literature discussions from the past fifty years
Complexity and Complex Ecological Systems is an extension of Elsevier's 2021 book Complexity and Complex Chemo-Electric Systems directed toward the analysis and synthesis of diverse ecological processes running in heterogeneous macrosystems. Contemporary advanced techniques such as averaged analysis, food webs approaches, and classical optimization results along with some numerical algorithms are commonly used in ecosystems. This book treats ecological systems as specific functional integrities. In Complexity and Complex Ecological Systems, one can observe how various types of ecological heterogeneities can contribute to flows of living and inanimate parts of the moving pseudo-continuum. This book is a valuable reference for scientists, engineers, and graduate students of environmental, chemical, and biological engineering, helping them better understand complex macroscopic systems and enhance their technical skills in theoretical and practical research. - Covers the basic aspects of modeling, analysis, synthesis, and optimization of ecological systems - Contains theory of selected ecosystems and explanations of how it can be used in applications - Includes original drawings and drafts that illustrate the properties of diverse ecosystems - Written by an expert in advanced methods of biophysics and macroscopic physics
Energy Optimization in Process Systems and Fuel Cells, Third Edition covers the optimization and integration of energy systems, with a particular focus on fuel cell technology. With rising energy prices, imminent energy shortages, and the increasing environmental impacts of energy production, energy optimization and systems integration is critically important. The book applies thermodynamics, kinetics and economics to study the effect of equipment size, environmental parameters, and economic factors on optimal power production and heat integration. Author Stanislaw Sieniutycz, highly recognized for his expertise and teaching, shows how costs can be substantially reduced, particularly in utilities common in the chemical industry. This third edition contains substantial revisions and modifications, with new material on catalytic reactors, sorption systems, sorbent or catalyst regenerators, dryers, and more. - Presents a unified approach to the optimization and integration of energy systems - Includes a large number of examples treating dynamical systems - Provides exposition showing the power of thermodynamics - Contains a large number of maximum power analyses and their extensions
Optimizing Thermal, Chemical and Environmental Systems treats the evaluation of power or energy limits for processes that arise in various thermal, chemical and environmental engineering systems (heat and mass exchangers, power converters, recovery units, solar collectors, mixture separators, chemical reactors, catalyst regenerators, etc.). The book is an indispensable source for researchers and students, providing the necessary information on what has been achieved to date in the field of process optimization, new research problems, and what kind of further studies should be developed within quite specialized optimizations. - Summarizes recent achievements of advanced optimization techniques - Links exergy definitions in reversible systems with classical problems of extremum work - Includes practical problems and illustrative examples to clarify applications - Provides a unified description of classical and work-assisted heat and mass exchangers - Written by a first-class expert in the field of advanced methods in thermodynamics
Energy Optimization in Process Systems and Fuel Cells, Second Edition" covers the optimization and integration of energy systems, with a particular focus on fuel cell technology. With rising energy prices, imminent energy shortages, and increasing environmental impacts of energy production, energy optimization and systems integration is critically important. The book applies thermodynamics, kinetics and economics to study the effect of equipment size, environmental parameters, and economic factors on optimal power production and heat integration. Author Stanislaw Sieniutycz, highly recognized for his expertise and teaching, shows how costs can be substantially reduced, particularly in utilities common in the chemical industry. This second edition contains substantial revisions, with particular focus on the rapid progress in the field of fuel cells, related energy theory, and recent advances in the optimization and control of fuel cell systems. New information on fuel cell theory, combined with the theory of flow energy systems, broadens the scope and usefulness of the bookDiscusses engineering applications including power generation, resource upgrading, radiation conversion, and chemical transformation in static and dynamic systemsContains practical applications of optimization methods that help solve the problems of power maximization and optimal use of energy and resources in chemical, mechanical, and environmental engineering
Scientists and engineers are nowadays faced with the problem of optimizing complex systems subject to constraints from, ecology, economics, and thermodynamics. It is chiefly to the last of these that this volume is addressed. Intended for physicists, chemists, and engineers, the book uses examples from solar, thermal, mechanical, chemical, and environmental engineering to focus on the use of thermodynamic criteria for optimizing energy conversion and transmission. The early chapters centre on solar energy conversion, the second section discusses the transfer and conversion of chemical energy, while the concluding chapters deal with geometric methods in thermodynamics.
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