The Chemistry of Heterocycles: Chemistry of Six to Eight Membered N,O, S, P and Se Heterocycles details the chemistry, behavior and potential of these important structures. The book presents a practical guide to international nomenclature, including discussions of fused ring systems, heteroatoms with abnormal valences, and bridged, spiro and polycyclic heterocycles. Three membered heterocycles are then the focus, along with their thermodynamic properties and importance in natural products, medicines, materials, and their unique aspects, such as strain, basicity and reactivity. Additional chapters cover 100 key heterocycle structures, from Azetidines, Pyrroles and Pyridines, to Benzoxepines and Oxocanes. Final chapters explore cutting-edge advances in the development of phosphorus and selenium based heterocycles. - Provides clear, detailed information on each heterocyclic group, including structural features, such as ring strain, basicity, synthesis and reactivity towards electrophilic and nucleophilic reagents - Highlights the latest advances in the field, including phosphorous and selenium-based heterocycles supported by numerous illustrations - Includes details of functionalized heterocycles used as synthons for the construction of various arenes and heteroarenes
Climate change and urbanization are two of the greatest challenges facing humanity in the 21st century, and their effects are converging in dangerous ways. Cities contribute significantly to global warming, and as the world further takes a rural-urban population tilt, the next few decades pose a great challenge in addressing global disparities in the access and allocation of carbon. This book explores the ways in which cities, through their spatial development, contribute to greenhouse gas (GHG) emissions and looks at the ways in which rapidly urbanizing cities in low- and middle-income countries can be planned to reduce overall GHG emissions. The book considers key questions such a: What should be the appropriate economies of scale for cities in a country? What is the most favourable rate of urbanization? What should be the most suitable spatial pattern for a city? And what are appropriate regulatory, economic or governance mechanisms to achieve a low-carbon society? These issues are explored through data analysis of over 156 developing countries and through a specific case study of India. India acts as an interesting example of how societies undergoing rural-to-urban transformations could become green within the planetary boundaries while systematically addressing national and local urban governance. The research concludes with a future pathway that is committed to low-carbon and high-equity spatial development, and will find pertinence to researchers and practitioners alike. This book provides a new tool for policymakers, planners and scholars to rationally and equitably account for global carbon space, prioritize low-carbon strategies for national urbanization and planning individual cities, in addition to recommending an urban governance framework inclusive of green agenda.
The Divided City contributes to the growing body of scholarly work on cities of the global South. Cities in developing countries, particularly emerging economies, are undergoing rapid urbanization and social transition. Empirically grounded to the contemporary urban situation in India, The Divided City is set in an opportune moment to assess how cities fare up to the challenge of inclusive urbanization. It highlights how the urban pathway of contemporary India departs from the goal of inclusion in multiple ways — access to energy, public services, architecture, land, infrastructure, commons, and cultural and civic spaces. It simultaneously interrogates both policy and theory with intermingling issues like informality, privatization, political economy and gender divide in the contemporary Indian city. The book argues for greater urban inclusion (social, economic and environmental) acknowledged in principle, in national and international urban policy frameworks.
This textbook employs a technical and quantitative approach to explain subsurface hydrology and hydrogeology, and to offer a comprehensive overview of groundwater-related topics such as flow in porous media, aquifer characterization, contaminant description and transport, risk assessment, and groundwater remediation. It describes the characterization of subsurface flow of pristine and polluted water and provides readers with easily applicable tools for the design of water supply systems, drinking-water source protection, and remediation interventions. Specific applications range from groundwater exploitation as a drinking water supply to the remediation of contaminated aquifers, from the definition and safeguarding of drinking-water sources to the assessment of human health risks in connection with groundwater contamination events. The book represents an ideal learning resource for upper-undergraduate and graduate students of civil engineering, environmental engineering, and geology, as well as practitioners in the fields of water resource management and environmental protection who are interested in groundwater engineering and technical hydrogeology.
Climate change and urbanization are two of the greatest challenges facing humanity in the 21st century, and their effects are converging in dangerous ways. Cities contribute significantly to global warming, and as the world further takes a rural-urban population tilt, the next few decades pose a great challenge in addressing global disparities in the access and allocation of carbon. This book explores the ways in which cities, through their spatial development, contribute to greenhouse gas (GHG) emissions and looks at the ways in which rapidly urbanizing cities in low- and middle-income countries can be planned to reduce overall GHG emissions. The book considers key questions such a: What should be the appropriate economies of scale for cities in a country? What is the most favourable rate of urbanization? What should be the most suitable spatial pattern for a city? And what are appropriate regulatory, economic or governance mechanisms to achieve a low-carbon society? These issues are explored through data analysis of over 156 developing countries and through a specific case study of India. India acts as an interesting example of how societies undergoing rural-to-urban transformations could become green within the planetary boundaries while systematically addressing national and local urban governance. The research concludes with a future pathway that is committed to low-carbon and high-equity spatial development, and will find pertinence to researchers and practitioners alike. This book provides a new tool for policymakers, planners and scholars to rationally and equitably account for global carbon space, prioritize low-carbon strategies for national urbanization and planning individual cities, in addition to recommending an urban governance framework inclusive of green agenda.
The national economic situation, rapidly changing societies, increasing environment pollution amidst global warming around us are some of the most burning topics in day-to-day discussions, news and scholarly discourses. What we see are only the consequences of protracted actions, policies and decisions. The issues associated with these phenomena are highly complex that challenge a direct interpretation of their root causations, indications, results and long-term impacts. For instance, is the issue of managing natural resources for industry & business operations within a country an economic problem? Or is it an ecological one? Or rather a social one? Could it be resolved with theories and techniques of either of these fields? Well, the issue and its redressal requires a combination of all the three disciplines. And yet actions to integrate all of these fields have typically by-passed one or more. The framework that has over the years most commonly explained the convergence of different spheres of disciplinary knowledge has been sustainability. At the same time, its pursuit in practice, the dominant public perception, political agendas and the mainstream media remains elusive. In absence of a critical theory on ‘sustainable societies’, the contemporary development model is misinformed by vague notions of greening, green growth, eco-development, ecotourism, smart cities, etc. largely steered by corporates and vested business groups. The contemporary societies exist and continue to develop without genuine knowledge about sustainability that lies fragmented in its contributing disciplinary streams. This book unfolds the inherent dilemmas, contradictions and paradoxes within the current sustainability paradigm to form a rather nuanced and inside view of what constitutes sustainability and how it could be realized with socio-technical, institutional, policy and management solutions. In the process, the research comprehensively reviews about a hundred environmental, social and economic theories to deliberate on the way forward. Considering that sustainability is a politico-economic and socio-cultural challenge, the transitions need to be culturally diverse and inter-generational, requiring infusion of fresh values, messaging and leadership while conserving traditional knowledge, prevailing institutions. The book culminates with a transition architecture bearing policy recommendations for governing without governmentality with plausible regulatory instruments, capacitating mechanisms, planning and voluntary measures that can be implemented in practice. Die nationale wirtschaftliche Situation, sich schnell verändernde Gesellschaften, die zunehmende Umweltverschmutzung inmitten der globalen Erwärmung um uns herum sind einige der brennendsten Themen in täglichen Diskussionen, Nachrichten und wissenschaftlichen Diskursen. Was wir sehen, sind nur die Folgen langwieriger Handlungen, Richtlinien und Entscheidungen. Die mit diesen Phänomenen verbundenen Fragen sind hochkomplex, die eine direkte Interpretation ihrer Ursachen, Indikationen, Ergebnisse und langfristigen Auswirkungen herausfordern. Ist zum Beispiel die Bewirtschaftung natürlicher Ressourcen für Industrie- und Geschäftsbetriebe innerhalb eines Landes ein wirtschaftliches Problem? Oder ist es ein ökologisches? Oder eher ein soziales? Könnte es mit Theorien und Techniken eines dieser Gebiete gelöst werden? Nun, das Problem und seine Abhilfe erfordert eine Kombination aller drei Disziplinen. Und dennoch haben Maßnahmen zur Integration all dieser Felder in der Regel eines oder mehrere umgangen. Der Rahmen, der im Laufe der Jahre am häufigsten die Konvergenz verschiedener Bereiche des disziplinären Wissens erklärt hat, war Nachhaltigkeit. Gleichzeitig bleibt ihre Verfolgung in der Praxis, die vorherrschende öffentliche Wahrnehmung, die politischen Agenden und die Mainstream-Medien schwer fassbar. In Ermangelung einer kritischen Theorie zu „nachhaltigen Gesellschaften“ wird das zeitgenössische Entwicklungsmodell durch vage Vorstellungen von Ökologisierung, grünem Wachstum, Öko-Entwicklung, Ökotourismus, Smart Cities usw., die größtenteils von Unternehmen und Konzernen gesteuert werden, falsch informiert. Die zeitgenössischen Gesellschaften existieren und entwickeln sich weiter, ohne echtes Wissen über Nachhaltigkeit, das in seinen disziplinären Strömungen zersplittert ist. Dieses Buch entfaltet die inhärenten Dilemmata, Widersprüche und Paradoxien innerhalb des aktuellen Nachhaltigkeitsparadigmas, um eine eher nuancierte Innenansicht dessen zu schaffen, was Nachhaltigkeit ausmacht und wie sie mit soziotechnischen, institutionellen, politischen und Managementlösungen realisiert werden könnte. Dabei überprüft die Forschung umfassend etwa hundert Umwelt-, Sozial- und Wirtschaftstheorien, um über das weitere Vorgehen nachzudenken. Angesichts der Tatsache, dass Nachhaltigkeit eine politisch-ökonomische und soziokulturelle Herausforderung ist, müssen die Übergänge kulturell vielfältig und generationenübergreifend sein, was die Einführung neuer Werte, Botschaften und Führung erfordert, während traditionelles Wissen und vorherrschende Institutionen erhalten bleiben. Das Buch gipfelt in einer Übergangsarchitektur mit Politikempfehlungen für ein Regieren ohne Gouvernementalität mit plausiblen Regulierungsinstrumenten, kapazitiven Mechanismen, Planungen und in der Praxis umsetzbaren freiwilligen Maßnahmen.
The Divided City contributes to the growing body of scholarly work on cities of the global South. Cities in developing countries, particularly emerging economies, are undergoing rapid urbanization and social transition. Empirically grounded to the contemporary urban situation in India, The Divided City is set in an opportune moment to assess how cities fare up to the challenge of inclusive urbanization. It highlights how the urban pathway of contemporary India departs from the goal of inclusion in multiple ways — access to energy, public services, architecture, land, infrastructure, commons, and cultural and civic spaces. It simultaneously interrogates both policy and theory with intermingling issues like informality, privatization, political economy and gender divide in the contemporary Indian city. The book argues for greater urban inclusion (social, economic and environmental) acknowledged in principle, in national and international urban policy frameworks.
Heterocycles are ubiquitously present in nature and occupy a unique place in organic chemistry as they are part of the DNA and haemoglobin that make life possible. The Chemistry of Heterocycles covers an introduction to the topic, followed by a chapter on the nomenclature of all classes of isolated, fused and polycyclic heterocycles. The third chapter delineates the highly strained three membered N,O and S containing aromatic and non-aromatic heterocycles with one and more than one similar and dissimilar heteroatom. The four-membered heterocycles are abundantly present in various natural and synthetic products of pharmacological importance. This chapter describes the natural abundance, synthesis, chemical reactivity, structural features and their medicinal importance. This class of compounds are present as sub-structures in penicillin and cytotoxic Taxol. Lastly, a chapter on the natural abundance, synthesis, chemical reactivity and pharmacological importance of 5-membered heterocycles with N,O,S heteroatom is covered. The chemistry of heterocycles with mixed heteroatom such as, N-S, N-O, N-S etc. is also described. - Gives in-depth, clear information about various systems of nomenclature along with widely acceptable IUPAC system for naming various classes of heterocycles - Provides complete information about natural occurrences, synthesis, chemical reactivity, pharmacological importance of heterocycles and their application in material science - Highly relevant for graduate students and researchers, providing updated information about various isolated and fused N,O and,S containing heterocycles
The Chemistry of Heterocycles: Chemistry of Six to Eight Membered N,O, S, P and Se Heterocycles details the chemistry, behavior and potential of these important structures. The book presents a practical guide to international nomenclature, including discussions of fused ring systems, heteroatoms with abnormal valences, and bridged, spiro and polycyclic heterocycles. Three membered heterocycles are then the focus, along with their thermodynamic properties and importance in natural products, medicines, materials, and their unique aspects, such as strain, basicity and reactivity. Additional chapters cover 100 key heterocycle structures, from Azetidines, Pyrroles and Pyridines, to Benzoxepines and Oxocanes. Final chapters explore cutting-edge advances in the development of phosphorus and selenium based heterocycles. - Provides clear, detailed information on each heterocyclic group, including structural features, such as ring strain, basicity, synthesis and reactivity towards electrophilic and nucleophilic reagents - Highlights the latest advances in the field, including phosphorous and selenium-based heterocycles supported by numerous illustrations - Includes details of functionalized heterocycles used as synthons for the construction of various arenes and heteroarenes
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