This book presents the analysis of up-to-date techniques used for the determination of acid-base properties in view of their applicability to examination of solid organic and inorganic surfaces. The studies have been carried out by the authors since 1993, showing experimental data on surface properties of more than 150 polymers, such as carbocatena
This book describes the fundamentals of fast liquid-phase chemical reactions and the principles of their scientific foundation, technical implementation and industrial application of new technologies. In addition, the equipment required to perform these reactions, in a turbulent mode in the chemical, petrochemical and petroleum industries, is also discussed. The macrokinetic approach has been developed with consideration of the diffusion, hydrodynamics, and heat transfer processes. Due to the advancement of fundamental knowledge, equations of practical engineering importance have been obtained for the calculations of mass and heat transfer processes carried out in conditions of high turbulence, and developed for the implementation in fast chemical reactions involving the synthesis of low molecular weight products and polymers. New methods for controlling the molecular characteristics of polymers have been developed based on the tailored regulation of the hydrodynamics of the reactive mixture flow. Typical processes have been used as model examples to reveal the influence of turbulence on the behaviour of fast chemical reactions used for the synthesis of low molecular weight products, in single-phase and two-phase reactive systems. Brand new tubular devices have been developed with the following characteristics: compact size, high productivity, and a quasi-perfect mixing operation mode in turbulent flows. These devices are subdivided into cylindrical, shell-and-tube, 'zone', and diffuser-confusor designs. Original solutions are proposed for the instrumental implementation of fast liquid-phase processes and development of continuous energy- and resource-efficient technologies for the synthesis of some large-scale compounds.
This book describes the fundamentals of fast liquid-phase chemical reactions and the principles of their scientific foundation, technical implementation and industrial application of new technologies. In addition, the equipment required to perform these reactions, in a turbulent mode in the chemical, petrochemical and petroleum industries, is also discussed. The macrokinetic approach has been developed with consideration of the diffusion, hydrodynamics, and heat transfer processes. Due to the advancement of fundamental knowledge, equations of practical engineering importance have been obtained for the calculations of mass and heat transfer processes carried out in conditions of high turbulence, and developed for the implementation in fast chemical reactions involving the synthesis of low molecular weight products and polymers. New methods for controlling the molecular characteristics of polymers have been developed based on the tailored regulation of the hydrodynamics of the reactive mixture flow. Typical processes have been used as model examples to reveal the influence of turbulence on the behaviour of fast chemical reactions used for the synthesis of low molecular weight products, in single-phase and two-phase reactive systems. Brand new tubular devices have been developed with the following characteristics: compact size, high productivity, and a quasi-perfect mixing operation mode in turbulent flows. These devices are subdivided into cylindrical, shell-and-tube, 'zone', and diffuser-confusor designs. Original solutions are proposed for the instrumental implementation of fast liquid-phase processes and development of continuous energy- and resource-efficient technologies for the synthesis of some large-scale compounds.
This book presents the analysis of up-to-date techniques used for the determination of acid-base properties in view of their applicability to examination of solid organic and inorganic surfaces. The studies have been carried out by the authors since 1993, showing experimental data on surface properties of more than 150 polymers, such as carbocatena
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