The power of electrochemical measurements in respect of thermodynamics, kinetics and analysis is widely recognized but the subject can be unpredictable to the novice even if they have a strong physical and chemical background, especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are perhaps wisely never attempted while the literature is sadly replete with flawed attempts at rigorous voltammetry.This textbook considers how to go about designing, explaining and interpreting experiments centered around various forms of voltammetry (cyclic, microelectrode, hydrodynamic, and so on). The reader is assumed to have a knowledge to Masters level of physical chemistry but no exposure to electrochemistry in general, or voltammetry in particular. While the book is designed to 'stand alone', references to important research papers are given to provide an entry into the literature.The book gives clear introductions to the theories of electron transfer and of diffusion in its early chapters. These are developed to interpret voltammetric experiments at macro-electrodes before considering microelectrode behavior. A subsequent chapter introduces convection and describes hydrodynamic electrodes. Later chapters describe the voltammetric measurement of homogeneous kinetics, the study of adsorption on electrodes and the use of voltammetry for electroanalysis.
Armin G Stromberg was arguably one of the founding fathers of the technique of stripping voltammetry frequently used in chemical analysis, yet he is virtually unheard of in Western scientific circles. He was a brilliant scientist, but due to his German ancestry he was interred in one of the NKVD GULAG camps at the outbreak of the Second World War.This semi-biographical history presents the complete set of 74 surviving letters written by Stromberg to his wife during this period. The letters provide both historians and the interested public with a rare and unique glimpse into the everyday living conditions of inmates in one of the GULAG labour camps. The book also traces Stromberg's life following his release. More importantly, it relates how he founded the thriving Tomsk school to the wider historical context of electroanalysis in the USSR, drawing conclusions about the rate of scientific development as compared to the West and showing how ‘wet analysis’ remained of vital importance to industry long after equivalent measurements were made elsewhere.Readers will also appreciate how Stromberg's invaluable contributions in the Tomsk School of Electroanalysis laid the foundations for the extensive metallurgical extraction and nuclear industries that dominated the entire Siberian region for many years. This book is a must-read for anyone interested in the life and times of an important, yet often overlooked scientist of the Second World War.
This is the first textbook in the field of electrochemistry that will teach experimental electrochemists how to carry out simulation of electrode processes. Processes at both macro- and micro-electrodes are examined and the simulation of both diffusion-only and diffusion-convection processes are addressed. The simulation of processes with coupled homogeneous kinetics and at microelectrode arrays are further discussed.Over the course of the book the reader's understanding is developed to the point where they will be able to undertake and solve research-level problems. The book leads the reader through from a basic understanding of the principles underlying electrochemical simulation to the development of computer programs which describe the complex processes found in voltammetry.This second edition has been revised throughout, and contains new material relating to random walks in electrochemistry, as well as expanded materials on the checking and validation of simulations, pulse techniques, and square wave voltammetry.
The field of electrochemical measurement, with respect to thermodynamics, kinetics and analysis, is widely recognised but the subject can be unpredictable to the novice, even if they have a strong physical and chemical background, especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are, perhaps wisely, never attempted, while the literature is sadly replete with flawed attempts at rigorous voltammetry.This book presents problems and worked solutions for a wide range of theoretical and experimental subjects in the field of voltammetry. The reader is assumed to have knowledge up to a Master's level of physical chemistry, but no exposure to electrochemistry in general, or voltammetry in particular, is required. The problems included range in difficulty from senior undergraduate to research level, and develop important practical approaches in voltammetry.The problems presented in the earlier chapters focus on the fundamental theories of thermodynamics, electron transfer and diffusion. Voltammetric experiments and their analysis are then considered, including extensive problems on both macroelectrode and microelectrode voltammetry. Convection, hydrodynamic electrodes, homogeneous kinetics, adsorption and electroanalytical applications are discussed in the later chapters, as well as problems on two rapidly developing fields of voltammetry: weakly supported media and nanoscale electrodes.There is huge interest in the experimental procedure of voltammetry at present, and yet no dedicated question and answer book with exclusive voltammetric focus exists, in spite of the inherent challenges of the subject. This book aims to fill that niche.
This is the first textbook in the field of electrochemistry that will teach experimental electrochemists how to carry out simulation of electrode processes. Processes at both macro- and micro-electrodes are examined and the simulation of both diffusion-only and diffusion-convection processes are addressed. The simulation of processes with coupled homogeneous kinetics and at microelectrode arrays are further discussed. Over the course of the book the reader's understanding is developed to the point where they will be able to undertake and solve research-level problems. The book leads the reader through from a basic understanding of the principles underlying electrochemical simulation to the development of computer programs which describe the complex processes found in voltammetry.This is the third book in the “Understanding Voltammetry” series, published with Imperial College Press and written by the Compton group. Other books in the series include “Understanding Voltammetry”, written by Richard G Compton with Craig Banks and also “Understanding Voltammetry: Problems and Solutions” (2012) written by Richard G Compton with Christopher Batchelor-McAuley and Edmund Dickinson. These are and continue to be successful textbooks for graduates in electrochemistry and electroanalytical studies.
About as noir as it can be...excellent' Frances Fyfield, Daily Telegraph The city is Los Angeles, the birthplace of the American dream, a city that has come to symbolize both heaven and hell. Billy McGrath is an enigma, half American, half English, who once dreamed of pursuing a career as an academic philosopher, but for the last fifteen years he's been a homicide detective -- one of LA's best. He knows the rules, and understands a justice system that punishes the underprivileged and lets the rich go free. He's an unhappy man, divorced from the wife he still adores and separated from a daughter for whom he'd willingly die. If he hasn't yet thought of suicide, he soon will. McGrath is called to a crime scene -- a woman dead on a kitchen floor in one of the city's seamiest neighbourhoods, an apparently routine assignment until he discovers that the murdered woman's son is LA's biggest crack dealer, an idol of the ghetto who offers him a one-million-dollar bounty for the name of the killer. Making the wrong choice for what might be the right reasons, McGrath initiates both his own fall from grace and, as he strives to redeem himself, a series of wild and furious actions that hurtle h
Shaquille O'Neal, today's hottest basketball star and media sensation, bringsthe ultimate starpower to his first motion picture, Blue Chips, starring NickNolte. This novelization tells the story of a basketball coach who bends NCAArules to scoop up the country's top three high school players.
This will help us customize your experience to showcase the most relevant content to your age group
Please select from below
Login
Not registered?
Sign up
Already registered?
Success – Your message will goes here
We'd love to hear from you!
Thank you for visiting our website. Would you like to provide feedback on how we could improve your experience?
This site does not use any third party cookies with one exception — it uses cookies from Google to deliver its services and to analyze traffic.Learn More.