Reinhard Haubold's Books

N Nitrogen

Compounds with Noble Gases and Hydrogen

By: Walter Hack,Reinhard Haubold,Ulrike Ohms-Bredemann,Claudia Heinrich-Sterzel,Hannelore Keller-Rudek,Dag Schiöberg,Carol Strametz

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N Nitrogen

Compounds with Noble Gases and Hydrogen

By: Walter Hack,Reinhard Haubold,Ulrike Ohms-Bredemann,Claudia Heinrich-Sterzel,Hannelore Keller-Rudek,Dag Schiöberg,Carol Strametz

Nitrogen" Suppt. Vol. B 1 describes the compounds of nitrogen with noble gases and, in the major part, binary compounds composed of one nitrogen atom and hydrogen. Nitrogen hydrogen compounds with two and more nitrogen atoms are covered in "Nitrogen" Suppt. Vol. 82. There is some information on various nitrogen-noble gas species, to a large extent because of the interest in their bonding behavior. Experimental data have been obtained chiefly for some singly charged cations, particularly those formed by argon Like ArN + and ArNi. The existence of others has only been established by mass spectrometry. The binary compounds of nitrogen and hydrogen comprise NH, NH , NH , NH , the corre 2 4 5 sponding ions, and some adducts. NH and NH1 are not treated. The predominant part 3 of the volume covers the description of the molecules NH and NH . 8oth species are present 2 in photolytic processes in the atmosphere. They play an essential role in combustion systems regardless of whether the nitrogen stems from the nitrogen-containing fuel or from the air. Thus, much work has been devoted to the understanding of the nitrogen chemistry in combustion and in the atmosphere. The production and detection methods as weiL as the reactions have been comprehensively described. ln addition detailed information is given on the spectral behavior, the knowledge of which is important for detecting the mole cules and for studying their kinetics.

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292

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Springer Science & Business Media

Published Date

ISBN 10

3662063336

ISBN 13

9783662063330

P Phosphorus

Mononuclear Compounds with Hydrogen

By: Werner Behrendt,Dieter Koschel,Hans Schäfer,Ulrich W. Gerwarth,Reinhard Haubold,Jörn v. Jouanne,Hannelore Keller-Rudeck,Joachim Wagner

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P Phosphorus

Mononuclear Compounds with Hydrogen

By: Werner Behrendt,Dieter Koschel,Hans Schäfer,Ulrich W. Gerwarth,Reinhard Haubold,Jörn v. Jouanne,Hannelore Keller-Rudeck,Joachim Wagner

This volume C 1 is the first supplement volume to "Phosphor" C which was published in 1965 and covers the compounds of phosphorus. Starting with the binary species formed between phosphorus and hydrogen, the present volume deals with the neutral mononuclear compounds PH through PH ; the ions featuring the same stoichiometric composition are s covered in separate sections. PH and PH are the major initial gaseous decomposition products of PH and, thus, also 2 J intermediates in many of its gas-phase reactions. Both molecules and their ions have been thoroughly investigated by a variety of modern, high-resolution spectroscopic methods during the last three decades. The coverage of their physical, and mostly molecular, properties re presents the largest part of the first two chapters (PH and ions pp. 2 to 47; PH and ions pp. 47 2 to 111). PH is the only compound described in this volume which is thermally stable under normal J conditions. It is the phosphorus analog of ammonia, but exhibits, however, a quite different chemical behavior towards most elements and compounds. The majority of its physical, and in particular spectroscopic, properties have been determined in great detail since the sixties, partially in regard to spectroscopic investigations of the atmospheres of the outer planets.

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Page Count

341

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Springer Science & Business Media

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ISBN 10

3662088479

ISBN 13

9783662088470

N Nitrogen

By: Reinhard Haubold,Peter Merlet,Claudia Heinrich-Sterzel,Astrid Wietelmann,Ulrike Ohms-Bredeman,Carol Strametz

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N Nitrogen

By: Reinhard Haubold,Peter Merlet,Claudia Heinrich-Sterzel,Astrid Wietelmann,Ulrike Ohms-Bredeman,Carol Strametz

This volume deals with binary nitrogen-hydrogen compounds having two, three, or more nitrogen atoms (with the exception of hydrazine) and with compounds composed of nitrogen, hydrogen, and noble gases. The important species containing two nitrogen atoms, N2H, N2H+, N2H2, and N2H3 are described in the first part of this volume. Next, chains and cycles consisting of three nitrogen atoms are covered. Among them hydrogen azide or hydrozoic acid, HN3, is the most extensively studied nitrogen-hydrogen compound described in this volume. With increasing number of nitrogen atoms, the thermochmical stability declines. There is, however, a considerable amount of information on molecules with up to nine linked nitrogen atoms. Several of these binary nitrogen-hydrogen compounds could only be isolated in the form of organic derivatives. In that case, data available for the organic derivatives were included if they were characteristic for the particular unsubstituted N-H parent compound.

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202

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Springer Science & Business Media

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ISBN 10

3662063360

ISBN 13

9783662063361

Compounds with Fluorine and Chlorine

By: Reinhard Haubold,Peter Merlet,Jörn v. Jouanne,Hannelore Keller-Rudek,Ulrike Ohms-Bredemann,Carol Strametz,Joachim Wagner,Astrid Wietelmann

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Compounds with Fluorine and Chlorine

By: Reinhard Haubold,Peter Merlet,Jörn v. Jouanne,Hannelore Keller-Rudek,Ulrike Ohms-Bredemann,Carol Strametz,Joachim Wagner,Astrid Wietelmann

The volume describes all compounds that consist of bromine and fluorine and/or chlorine and may additionally contain noble gases, hydrogen, oxygen, and nitrogen. The description of chemical and physical properties of binary compounds between bromine and fluorine takes up most of the volume, because this class of compounds includes BrF3 and BrF5 which have considerable technical interest. Especially the the oxidizing and fluorinating properties of BrF3 make it a convenient reactant for the preparation of inorganic fluorides. On the other hand, the diatomic molecule BrF is well-characterized by spectroscopic methods, but its chemistry is less known because of its instability. Other neutral species, such as Br2F, Br2F2, BrF2, and BrF6, only exist in matrices at low temperatures, and the existence of BrF4 and BrF7 is even doubted. Some of the ions, including BrF2+, BrF2-, Br3F10-, BrF4+, BrF4-, BrF6+, and BrF6-, can be stabilized as salts.

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272

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Springer

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ISBN 10

3540936424

ISBN 13

9783540936428

Di- and Polynuclear Compounds 5

By: Ulf Thewalt,Reinhard Hemmer

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Di- and Polynuclear Compounds 5

By: Ulf Thewalt,Reinhard Hemmer

The present volume is the fifth and for the present moment last in a series of volumes on organotitanium compounds. It covers the literature to the end of 1987. The volume continues the treatment of titanium compounds with the dinuclear and polynuclear complexes. The main part of this volume deals with the dinuclear complexes and therein (+-C5H5)2TiCl 2 is the most frequently described compound. Another key compound in this volume is the presumably oligomeric +-C5H5TiCl2 n. This volume also deals with different "titanocenes" de- scribed in the literature. There are also well-defined tri- and tetranuclear compounds, one penta- and a few hexanuclear compounds. "Black titanocene" is described together with the oligonuclear compounds. Polymers containing (+-C5H5)2TiIV units conclude this volume. As in the preceding volumes of this series, compounds of debatable existence and postulated reaction intermediates are included for completeness. A Formula Index and a Ligand Formula Index for this volume are included.

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432

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Springer Science & Business Media

Published Date

ISBN 10

366206572X

ISBN 13

9783662065723

Re Organorhenium Compounds

By: Reinhard Albrecht

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Re Organorhenium Compounds

By: Reinhard Albrecht

The present volume belongs to a series of handbooks dealing with organorhenium com pounds. 1t covers the Literature up to the end of 1993, but some more recent data published in 1994 have also been considered. Patents, conference reports, and dissertations generally were not reviewed. An empirical formula index, a Ligand formula index, and a transition metals cross reference table provide ready access to all compounds covered. The following comments may be helpful for rapidly finding the compound(s) you wish to get information of. ln the Gmelin series "Organometallic Compounds" the term "organometallic" is re served for all compounds containing at Least one carbon-to-metal bond. For all volumes published in this series, see p. VI. The series on organorhenium compounds started with the description of mononuclear compounds in Volumes 1 to 4 (Volume 4 is still to be published) and continues with the present Volume 5 describing all binuclear organorhenium compounds having 0 to 10 CO groups as Ligands, except (C0) Re which will be included in the next volume together 10 2 with all other binuclear compounds having carbenes, isonitriles, and "L Ligands (n > 1) bonded to rhenium as weiL as all other polynuclear organorhenium compounds.

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555

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Springer Science & Business Media

Published Date

ISBN 10

3662060523

ISBN 13

9783662060520

Ternary Silicon-Fluorine-Hydrogen Compounds

By: Reinhard Haubold,Werner Behrendt,Friedrich Schröder,Hans Schäfer,Hannelore Keller-Rudek,Sigrid Ruprecht

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Ternary Silicon-Fluorine-Hydrogen Compounds

By: Reinhard Haubold,Werner Behrendt,Friedrich Schröder,Hans Schäfer,Hannelore Keller-Rudek,Sigrid Ruprecht

The volume provides complete and up-to-date information on the few chemical species composed of silicon, fluorine, and noble gases and in the major part on the species composed of silicon, fluorine, and hydrogen. Among the numerous experimentally confirmed and theoretically predicted monosilicon Si-H-F species with Si coordination numbers 2, 3, and 4, the most prominent and best investigated molecules by far are Si H3F, Si H2F2, and Si H F3. Even more has been reported about aqueous solutions of hexafluorosilicic acid, "H2Si F6", a system which is not yet completely understood. Some of the isomers of partially fluorinated di-, tri-, and tetrasilanes are known to some extent, but information on the higher acyclic and cyclic polysilanes is increasingly sparce.

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