Rainer Mahrwald's Books

Aldol Reactions

By: Rainer Mahrwald

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Aldol Reactions provides a comprehensive up-to-date overview of aldol reactions including application of different metal enolates; catalytic aldol additions catalyzed by different Lewis acids and Lewis bases; enantioselective direct aldol additions; antibodies and enzyme catalyzed aldol additions and the recent aggressive development of organocatalyzed aldol additions. The power of each method is demonstrated by several applications in total synthesis of natural products. The pros and cons of these methodologies with regard to stereoselectivity, regioselectivity and application in total synthesis of natural products are discussed. Great importance is set to the diverse possibilities of the manual of aldol reaction to install required configurations in complicated natural product synthesis.

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Page Count

214

Publisher

Springer Science & Business Media

Published Date

ISBN 10

1402087012

ISBN 13

9781402087011

Modern Organocatalyzed Methods in Carbohydrate Chemistry

By: Rainer Mahrwald

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Modern Organocatalyzed Methods in Carbohydrate Chemistry

By: Rainer Mahrwald

This brief presents a valuable and concise overview of organocatalytic methodologies in carbohydrate chemistry. It includes glycosylation processes with de novo syntheses of carbohydrates and chain elongation of carbohydrates. The author, an academic of international distinction, goes on to make comparisons between traditional organic and metalorganic transformations.

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Springer

Published Date

ISBN 10

3319175939

ISBN 13

9783319175935

Enantioselective Organocatalyzed Reactions I

Enantioselective Oxidation, Reduction, Functionalization and Desymmetrization

By: Rainer Mahrwald

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Enantioselective Organocatalyzed Reactions I

Enantioselective Oxidation, Reduction, Functionalization and Desymmetrization

By: Rainer Mahrwald

Organocatalyzed Reactions I and II presents a timely summary of organocatalysed reactions including: a) Enantioselective C-C bond formation processes e.g. Michael-addition, Mannich-reaction, Hydrocyanation (Strecker-reaction), aldol reaction, allylation, cycloadditions, aza-Diels-Alder reactions, benzoin condensation, Stetter reaction, conjugative Umpolung, asymmetric Friedel-Crafts reactions; b) Asymmetric enantioselective reduction processes e.g. Reductive amination of aldehydes or ketones, asymmetric transfer hydrogenation; c) Asymmetric enantioselective oxidation processes; d) Asymmetric epoxidation, Bayer-Villiger oxidation; e) Enantioselective a-functionalization; f) A-alkylation of ketones, a-halogenation and a-oxidation of carbonyl compounds.

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