This book bridges the gap between sophomore and advanced / graduate level organic chemistry courses, providing students with a necessary background to begin research in either an industry or academic environment. • Covers key concepts that include retrosynthesis, conformational analysis, and functional group transformations as well as presents the latest developments in organometallic chemistry and C–C bond formation • Uses a concise and easy-to-read style, with many illustrated examples • Updates material, examples, and references from the first edition • Adds coverage of organocatalysts and organometallic reagents
Hat utopisches Denken einen Platz in der Ökonomik? In welchem Verhältnis stehen utopische Entwürfe in der Kunst und wirtschaftswissenschaftliche Theoriebildung? Ökonomische Utopien untersucht die spezifische Rolle ökonomischer Theorie und Praxis im utopischen Diskurs der Moderne – und umgekehrt: die Spuren utopischen Denkens in der Ökonomik seit Beginn einer im modernen Sinn als kapitalistisch zu bezeichnenden Wirtschaftsweise. Wie facettenreich die Beziehungen zwischen Utopie und Ökonomie tatsächlich sind, zeigt das breite thematische Spektrum, das von den Autorinnen und Autoren aus Kultur-, Sozial- und Wirtschaftswissenschaften verhandelt wird: Es reicht von anarchokommunistischen Öko-Utopien der Gegenwartsliteratur bis zu Maschinenmenschen in der Malerei, von ökonomisch-utopischen Diskursen in der Populärkultur bis zu den Ideen des kybernetischen Sozialismus, von der philosophischen Reflexion des Glücksspiels als inner- und gegenkapitalistische Utopie bis hin zur Diskussion utopischer Dimensionen heutiger neoklassischer Wirtschaftstheorie. Die Beiträge zeigen, wie pragmatische und normative Motivationen bei der Entwicklung alternativer Wirtschaftsentwürfe ineinander greifen und dass es sich bei ökonomischen Utopien auch um lokale, individuelle, momentane Strategien handeln kann, die der durch Rationalität und Lohnarbeit gekennzeichneten Realität alternative Lebensentwürfe entgegenhalten.
Nuclear Magnetic Resonance Spectroscopy, Second Edition focuses on two-dimensional nuclear magnetic resonance (NMR) spectroscopy, high resolution NMR of solids, water suppression, multiple quantum spectroscopy, and NMR imaging. The selection first takes a look at the fundamental principles and experimental methods. Discussions focus on the NMR phenomenon, dipolar broadening and spin-spin relaxation, nuclear electric quadrupole relaxation, saturation, magnetic shielding and chemical shift, magnetic field, transitions between the nuclear energy levels, and resolution and sensitivity considerations. The manuscript then ponders on chemical shift, coupling of nuclear spins, and nuclear relaxation and chemical rate processes. Topics include spin lattice relaxation, spin-spin relaxation, spin decoupling and associated techniques, and description and analysis of spin systems. The text examines two-dimensional NMR spectroscopy, macromolecules, and NMR of solids, including magic angle spinning, cross polarization, proton dipolar broadening, biopolymers, and chain motion in macromolecules. The selection is a valuable source of data for readers interested in nuclear magnetic resonance spectroscopy.
This volume starts the updating of the information on organonickel chemistry, one of the most active areas of modern organometallic chemistry. It covers all mononuclear compounds containing one nickel-to-carbon bond. The main part is devoted to the family of planar NiII compounds, RNi(D)2X, which within 20 years has increased from about 250 to more than 1000 members. This research interest has been stimulated by the fact that many compounds insert various unsaturated species into the Ni-C bond to create new organonickel species. Moreover, these compounds are important as intermediates in many catalytic processes involving organic halides. Compounds containing h*2-bonded heteroalkene molecules including the C1 fragments CO2 and CS2, and related metallocyclic compounds are also emphasized in this volume. These types of compounds play an important role in a number of nickel-catalyzed co-oligomerization reactions involving unsaturated organic compounds. Most of the compounds are well-characterized by modern spectroscopic techniques. The various types of compounds are in most cases confirmed by X-ray diffraction. The author of these volumes, a member of the M lheim group, has made many contributions of his own and is eminently qualified to critically review this area of research.
Most literature pertaining to carbon fibers is of a theoretical nature. Carbon Fibers and their Composites offers a comprehensive look at the specific manufacturing of carbon fibers and graphite fibers into the growing surge of diverse applications that include flameproof materials, protective coatings, biomedical and prosthetics application
The volume is concerned exclusively with all the binary species formed between the elements silicon and fluorine such as SiF, SiF2, SiF3, SiF4, and Sif62-. Most of the volume, i.e. 144 pages, is devoted to the description of the well known physical and chemical properties of the SiF4 as well as to its preparation. This is followed in length by the report on SiF2 with its interesting chemistry, along with a section on the diatomic radical SiF. Species with fivefold and sixfold coordination of silicon are exemplified by SiF5- and by the well known SiF62-. Interestingly, the detailed models for describing the bonding situation in both ions are still a matter of discussion. While for Si2F6 most of the basic data are known, information on the chemical and physical properties of the higher members of the acylic perfluorosilanes, SinF2n+2, is scarce. All available information on the unstable cyclic perfluorosilanes of composition (SiF2)n and some even more exotic species is also included.
Europe is a word that is almost daily on our lips. But how far do we have to go back in order to find the origins of its name? The first part of this beautifully illustrated book traces the geographical and mythological basis of Europe's name. Who came up with the idea to distinguish the world in continents with proper names? The search will bring the reader back to the early history of mankind. How did the ancient Egyptians see the world and populations around them? Where did the Hebrews get the idea to split the world in three? And what was the world-picture in ancient Greece, laid down in geographic treatises and fragments? Where did the name 'Europe' originate from? Could it be from a person, either mortal or divine? In ancient Greek literature the name 'Europa' appears quite frequently for Greek goddesses and Greek women. Strangely enough, the best known Europa myth concerns a Phoenician princess, loved by the Greek god Zeus. Many mythographs doubt the Asian descent of the Phoenician Europa. Is her real origin to be located on mainland Greece? How can the contradicting Greek myths be interpreted, and was the name universally accepted as the name for the continent? In the second part of this book, the author tells the amazing story of how the Arts have treated the Europa myths for almost three millennia. He shows the extraordinary influence of the personification of the geographic continent Europe on literature, music, sculpture, painting, tapestry and other applied arts. All this clearly demonstrates the vivid interest in Europe for the subject throughout the ages and illustrates, according to Karel van Miert in his Foreword, our common European culture.
This completely updated and enlarged third edition of the classic text adopts a practical approach to describe the fundamentals of freeze-drying, backed by many explanatory examples. Following an introduction to the fundamentals, the book goes on to discuss process and plant automation as well as methods to transfer pilot plant qualifications and process data to production. An entire section is devoted to a large range of different pharmaceutical, biological, and medical products. New to this edition are chapters on antibodies, freeze-dry microscopy, TEMPRIS, microwave freeze-drying, spray freeze-drying, and PAT. Their many years of experience in freeze-drying enable the authors to supply valuable criteria for the selection of laboratory, pilot and production plants, discussing the advantages, drawbacks and limitations of different plant designs. Alongside guidelines for the evaluation and qualification of plants and processes, the author also includes a troubleshooting section.
List of Abbreviations. Preface and Acknowledgements. The Importance Of Being Gilberto. Portrait of the Artist as a Young Man. Masters and Slaves. A Public Intellectual. Empire and Republic. The Social Theorist. Gilberto Our Contemporary. Chronology. Notes. Further Reading. Index.
The book of Second Peter has long troubled biblical scholars and interpreters, who have disputed both its authorship and its claims about the imminent return of Christ. In this study, Peter Leithart offers a preterist reading of the epistle, arguing that it describe first-century events rather than the end of history. At the same time, he maintains orthodoxy, avoiding hyper-preterism and affirming both the real future return of Christ and the epistle's authenticity. Leithart's accessible style and powerful arguments make this book a valuable addition to the discussion surrounding the Bible's apocalyptic prophecies.
All thoughtful leaders can admit experiences of ongoing incompetence--dilemmas, decisions, and even debacles that make them question how they became leaders in the first place. When we look at St. Peter, however, we see a great leader who engaged with his weaknesses and knew his shortcomings. By following his example, we become better leaders in any arena. Seminary president Peter Lillback's profound treatment of more than 100 principles drawn from St. Peter helps you to think through your management style, communication, decision-making, and more. Practical spiritual exercises put the lessons of each short chapter into action--bringing joy to our hearts, guidance to our lives, and help to our service"--From publisher's description.
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