Many chemists and biochemists require to know the ionization constants of organic acids and bases. This is evident from the Science Citation Index which lists The Determination of Ionization Constants by A. Albert and E. P. Serjeant (1971) as one of the most widely quoted books in the chemical literature. Although, ultimately, there is no satisfactory alternative to experimental measurement, it is not always convenient or practicable to make the necessary measure ments and calculations. Moreover, the massive pK. compilations currently available provide values for only a small fraction of known or possible acids or bases. For example, the compilations listed in Section 1. 3 give pK. data for some 6 000--8 000 acids, whereas if the conservative estimate is made that there are one hundred different substituent groups available to substitute in the benzene ring of benzoic acid, approximately five million tri-substituted benzoic acids are theoretically possible. Thus we have long felt that it is useful to consider methods by which a pK. value might be predicted as an interim value to within several tenths of a pH unit using arguments based on linear free energy relationships, by analogy, by extrapolation, by interpolation from existing data, or in some other way. This degree of precision may be adequate for many purposes such as the recording of spectra of pure species (as anion, neutral molecule or cation), for selection of conditions favourable to solvent extraction, and for the interpretation of pH-profiles for organic reactions.
An eccentric young caretaker brings exuberant life to a smalltown French cemetery in this #1 international bestselling novel: “Enchanting” (Publishers Weekly). Violette Toussaint is the caretaker at a cemetery in a small town in Bourgogne, France. Traversing the grounds by unicycle, tending to her many gardens—and being present for the intimate, often humorous confidences of visitors—Violette’s life follows the predictable rhythms of mourning. But then Violette’s routine is disrupted by the arrival of Julien Sole, the local police chief. Julien has come to scatter the ashes of his recently deceased mother on the gravesite of a complete stranger. It soon becomes clear that Julien’s inexplicable gesture is intertwined with Violette’s own complicated past. “Melancholic and yet ebullient . . . An appealing indulgence in nature, food and drink, and, above all, friendships.” —The Guardian, UK
These essays, all concerned with countryish things, range from intensely practical to mildly literary. Transplanted from New York fifteen years ago and now a real-life Vermont farmer, Noel Perrin candidly admits to hilarious early mistakes ("In Search of the Perfect Fence Post") while presenting down-to-earth advice on such rural necessities as "Sugaring on $15 a Year," "Raising Sheep," and "Making Butter in the Kitchen." But, as everyone who has read his essays in The New Yorker, Country Journal, and Vermont Life will confirm, not everything Perrin writes is strictly about the exigencies of country life. While one essay seems to discuss the use of wooden sap buckets, it really addresses the nature of illusion and reality as they coexist in rural places.
Examination of Musculoskeletal Injuries, Fourth Edition, guides current and future athletic trainers and rehabilitation professionals through the examination and evaluation of musculoskeletal injuries both on and off the field.
NATIONAL BESTSELLER SHORTLISTED for the 2021 BC Book Awards' George Ryga Award for Social Awareness in Literature SHORTLISTED for the BC and Yukon Book Prizes, for both the Hubert Evans Non-Fiction Prize and Jim Deva Prize for Writing That Provokes SHORTLISTED for the 2021 J. W. Dafoe Book Prize SHORTLISTED for the 2020 Lane Anderson Award “Overdose is a necessary and searching investigation into a devastating epidemic that should never have happened. Benjamin Perrin painstakingly shows that it need not continue if we, as a society, heed the evidence.” —Gabor Maté M.D., author of In The Realm of Hungry Ghosts: Close Encounters With Addiction An astonishing and powerful look at the ongoing opioid crisis North America is in the middle of a health emergency. Life expectancies are declining. Someone is dying every two hours in Canada from illicit drug overdose. Fentanyl has become a looming presence—an opioid more powerful, pervasive, and deadly than any previous street drug. The victims are many—and often not whom we might expect. They include the poor and forgotten but also our neighbours: professionals, students, and parents. Despite the thousands of deaths, these victims have remained largely invisible. But not anymore. Benjamin Perrin, a law and policy expert, shines a light in this darkest of corners—and his findings challenge many assumptions about the crisis. Why do people use drugs despite the risk of overdosing? Can we crack down on the fentanyl supply? Do supervised consumption sites and providing “safe drugs” enable the problem? Which treatments work? Would decriminalizing all drugs help or do further harm? In this urgent and humane look at a devastating epidemic, Perrin draws on behind-the-scenes interviews with those on the frontlines, including undercover police officers, intelligence analysts, border agents, prosecutors, healthcare professionals, Indigenous organizations, activists, and people who use drugs. Not only does he unveil the many complexities of this situation, but he also offers a new way forward—one that may save thousands of lives.
Proven techniques and principles for modernizing legacy systems into new architectures that deliver serious competitive advantage. For a business to thrive, it needs a modern software architecture that is aligned with its corporate architecture. This book presents concrete practices that sync software, product, strategy, team dynamics, and work practices. You’ll evolve your technical and social architecture together, reducing needless dependencies and achieving faster flow of innovation across your organization. In Architecture Modernization: Socio-technical alignment of software, strategy, and structure you’ll learn how to: Identify strategic ambitions and challenges using listening and mapping tours Visualize your business landscape and crucial capabilities with Wardley Mapping Create a product taxonomy as a framework for your architecture Run big picture EventStorming workshops to map business domains Apply Team Topologies patterns to identify and refine value streams Design loosely coupled, domain-aligned software architectures Build internal developer platforms for rapid, reliable evolution Implement data mesh principles and tools to revolutionize data engineering Deliver compelling modernization roadmaps focused on continuous value Architecture Modernization: Socio-technical alignment of software, strategy, and structure shows you how to turn the practice of architecting systems into a transformative process for your entire company. Chapter-by-chapter, you’ll identify the reasons and benefits of modernization, design an architecture that works for your business, and then implement your new approach in a progressive and sustainable manner. Every technique is illustrated with insightful industry examples and an interactive Miro board that lets you dig deeper. Forewords by Matthew Skelton and Xin Yao. About the technology The decisions you make about your software are inherently connected to the decisions you make about your business. Why not turn the mundane task of modernizing legacy systems into a transformative process for your entire company? This book shows you how! It reveals a socio-technical approach to align your software and products with organizational dynamics and ways of working. About the book Architecture Modernization: Socio-technical alignment of software, strategy, and structure presents a clear path for upgrading your entire organization when you re-imagine your software. In it, you’ll learn to combine practices like Domain-Driven Design, Event Storming, and Wardley Mapping to discover user needs, design optimal architecture, and avoid falling back into old habits. Provocative examples from Danske, Salesforce, the UK Government, and others show the real-world result of each approach, identifying techniques you can apply effectively in your own business. About the reader For CTOs, tech leads, and principal engineers who decide on architecture and organization design. About the author Nick Tune helps organizations modernize their architectures through empowered product teams and continuous delivery. Jean-Georges Perrin builds innovative and modern data platforms. The technical editor on this book was Kamil Nicieja.
This book proposes that the "Gospel of Thomas" depends on the second-century Syriac "Diatessaron," rules out Thomas as a meaningful source for Historical Jesus research, and suggests links between Thomas and other literature of the ancient near east. Paperback edition is available from the Society of Biblical Literature (www.sbl-site.org).
Emerging from thought-provoking discussions and correspondence Simone Weil had with the Reverend Father Perrin, this classic collection of essays contains her most profound meditations on the relationship of human life to the realm of the transcendant. An enlightening introduction by Leslie Fiedler examines Weil's extraordinary roles as a philosophy teacher turned mystic. "One of the most neglected resources of our century ", Waiting for God will continue to influence spiritual and political thought for centuries to come.
II ne fallait pas jouer à ce petit jeu, Jessie. Vous voilà enchaînée sur votre lit, le cadavre de Gerald à vos pieds, condamnée à vous enfoncer dans la nuit, la terreur et la folie. Les femmes seules dans le noir sont comme des portes ouvertes... si elles appellent à l'aide, qui sait quelles créatures horribles leur répondront ? Aucun des précédents romans de King ne prépare au huis-clos terrifiant de Jessie, à cette lente exploration de nos phobies et de nos cauchemars les plus sombres. L'histoire de Jessie, sa dernière victime, montre à quel point il ne faut avoir peur que de soi-même.
&To those who went to the War straight from school and survived it, the problem of what to do afterwards was particularly difficult.&’ For H.W. Tilman, the solution lay in Africa & gold prospecting, mountaineering and a 3,000-mile solo bicycle ride across the continent. Tilman was perhaps the greatest explorer of his time, a famed mountaineer and pioneering sailor who made first ascents throughout the Himalaya, attempted Everest, and sailed into the Arctic Circle. For Tilman, the goal was always to discover new places, to explore rather than conquer. Snow on the Equator chronicles Tilman&’s early adventures; his transition from East African coffee planter to famed mountaineer. After World War I, he moved to Africa, meeting Eric Shipton and beginning a hugely successful mountaineering partnership. He hunted game, experimented with mining and climbed Mount Kenya, Kilimanjaro and Ruwenzori before embarking on a remarkable bicycle odyssey across Africa & recounted here in splendidly funny style. Tilman became one of the greatest of all travel writers. His writings are the works of a subtle and wry humourist with an ironic, yet cultured and committed world view. He is part of the great British tradition of comic writing & and there is nobody else quite like him.
America’s Health Care Crisis Solved highlights the major pitfalls of our current health care system and shows why, without changes, health care costs will soon demolish the American economy as well as the opportunity to receive quality care. However, contrary to the increasingly popular idea of a government health plan, the alternative presented by authors J. Patrick Rooney and Dan Perrin brings the self-interest of you, the American consumer, into the equation.
As she explains, "If the iconic influence that surrounds metaphor is set aside, the results will be greater understanding and interpretations that are less opaque."".
War can get a fellow killed. The fearless draconians of the War of the Lance have retired from the field of battle to a pleasant valley in the Kharolis Mountains. Well, it would be pleasant, if it weren't for some dwarves, whose irritating feuding prevents the draconians from realizing their greatest hope -- the ability to continue their doomed race. When the dwarves discover a map leading to a fortune buried in the dwarven kingdom of Thorbardin, the draconians are swept up in a feverish race for treasure. Little do both sides realize that they are part of the strange and terrible destiny descending upon Krynn during the Summer of Flame. A desinty that includes the children of Chaos . . . the fire dragons! The Doom Brigade is the first installment in The Chaos War series, stories set during the war of the Dragons of Summer Flame, the New York Times best-selling novel co-authored by Margaret Weis.
Sexual reproduction is a fundamental aspect of life. It is defined by the occurrence of meiosis and the fusion of two gametes of different sexes or mating types. Sex-determination mechanisms are responsible for the sexual fate and development of sexual characteristics in an organism, be it a unicellular alga, a plant, or an animal. In many cases, sex determination is genetic: males and females have different alleles or different genes that specify their sexual morphology. In animals, this is often accompanied by chromosomal differences. In other cases, sex may be determined by environmental (e.g. temperature) or social variables (e.g. the size of an organism relative to other members of its population). Surprisingly, sex-determination mechanisms are not evolutionarily conserved but are bewilderingly diverse and appear to have had rapid turnover rates during evolution. Evolutionary biologists continue to seek a solution to this conundrum. What drives the surprising dynamics of such a fundamental process that always leads to the same outcome: two sex types, male and female? The answer is complex but the ongoing genomic revolution has already greatly increased our knowledge of sex-determination systems and sex chromosomes in recent years. This novel book presents and synthesizes our current understanding, and clearly shows that sex-determination evolution will remain a dynamic field of future research. The Evolution of Sex Determination is an advanced, research level text suitable for graduate students and researchers in genetics, developmental biology, and evolution.
Thoroughly updated and expanded, the Second Edition of Child Maltreatment: An Introduction disseminates current knowledge about the various types of violence against children. Uniquely offering both a psychological and sociological focus, this core text helps students understand more fully the etiology, prevalence, treatment, policy issues, and prevention of child maltreatment.
The premier text for athletic taping and bracing is now revised in a stunning third edition. Athletic Taping and Bracing retains its emphasis on the techniques most commonly used by athletic trainers and therapists while integrating the science of anatomy and injury mechanisms with the practice of athletic taping and bracing. Plus, the third edition expands on traditional taping by including methods for rigid strap taping and elastic kinesiology taping. Athletic Taping and Bracing, Third Edition, includes more than 480 full-color illustrations and photos, providing invaluable visual aids for both students and professionals. These include superb three-dimensional anatomical images from Primal Pictures. The photos that depict taping sequences feature tape with darkened edges that enable readers to distinguish the layers and patterns of the tape applied in each step. With its concise anatomical descriptions and detailed anatomical illustrations similar to those normally found in advanced texts on anatomy, the book clearly highlights the mechanisms of injury that are crucial for understanding effective taping and bracing. The text thoroughly discusses and illustrates the general principles of taping and bracing for each major joint and body region. The third edition adds step-by-step instructions for 10 additional techniques, including elastic kinesiology taping and rigid strap taping techniques for gastrocnemius strains, Achilles tendinitis, and arch problems; knee, quadriceps, and hip problems; shoulder and elbow hyperextension laxity; epicondylitis; and wrist and hand issues. The book also features newly added instructor resources consisting of an image bank and testing checklists to help students master the taping procedures. The text covers the 46 most frequently applied taping and bracing procedures in clinical practice, some of which are broken down into as many as 16 steps. It illustrates procedures for fabricating protective pads and orthotics, and it details the dos and don’ts of taping and bracing. To emphasize rehabilitation as well as prevention, Athletic Taping and Bracing, Third Edition, also presents basic stretching and strengthening exercises for injury rehabilitation. These exercises, presented and illustrated for each body part, focus on flexibility, strength, and proprioception. Combined with the taping and bracing procedures, the exercises will help rehabilitated athletes maintain strength and flexibility and safely return to play.With Athletic Taping and Bracing, Third Edition, readers will learn the evidence-based foundations and techniques of taping and bracing, as well as how taping and bracing can aid an athlete’s total rehabilitation. The coverage of rehabilitation exercises as well as prevention will help readers become more effective health care providers for athletes and other active people with musculoskeletal injuries and problems.
Named most aniticpated by: Barnes & Noble, Goodreads, BookRiot, BookBub, The Nerd Daily, Shelf Reflection, Novel Suspects, Borrow Read Repeat, The Everygirl, The Scout Guide, The Real Book Spy The Top LibraryReads pick for March 2024 A Publishers Marketplace 2024 BuzzBook For fans of Knives Out and The Thursday Murder Club, an enormously fun mystery about a woman who spends her entire life trying to prevent her foretold murder only to be proven right sixty years later, when she is found dead in her sprawling country estate.... Now it's up to her great-niece to catch the killer. It’s 1965 and teenage Frances Adams is at an English country fair with her two best friends. But Frances’s night takes a hairpin turn when a fortune-teller makes a bone-chilling prediction: One day, Frances will be murdered. Frances spends a lifetime trying to solve a crime that hasn’t happened yet, compiling dirt on every person who crosses her path in an effort to prevent her own demise. For decades, no one takes Frances seriously, until nearly sixty years later, when Frances is found murdered, like she always said she would be. In the present day, Annie Adams has been summoned to a meeting at the sprawling country estate of her wealthy and reclusive great-aunt Frances. But by the time Annie arrives in the quaint English village of Castle Knoll, Frances is already dead. Annie is determined to catch the killer, but thanks to Frances’s lifelong habit of digging up secrets and lies, it seems every endearing and eccentric villager might just have a motive for her murder. Can Annie safely unravel the dark mystery at the heart of Castle Knoll, or will dredging up the past throw her into the path of a killer? As Annie gets closer to the truth, and closer to the danger, she starts to fear she might inherit her aunt’s fate instead of her fortune.
The Dictionary of Jesus and the Gospels is unique among reference books on the Bible, the first volume of its kind since James Hastings published his Dictionary of Christ and the Gospels in 1909. In the more than eight decades since Hastings, our understanding of Jesus, the Evangelists and their world has grown remarkably. New interpretive methods illumined the text, the ever-changing profile of modern culture has put new questions to the Gospels, and our understanding of the Judaism of Jesus's day has advanced in ways that could not have been predicted in Hastings's day. But for many readers of the Gospels the new outlook on the Gospels remains hidden within technical journals and academic monographs. The Dictionary of Jesus and the Gospels bridges the gap between scholars and those pastors, teachers, students and lay people desiring in-depth treatment of select topics in an accessible and summary format. The topics range from cross-sectional themes (such as faith, law, Sabbath) to methods of interpretation (such as form criticism, redaction criticism, sociological approaches), from key events (such as the birth, temptation and death of Jesus) to each of the four Gospels as a whole. Some articles - such as the Dead Sea Scrolls, rabbinic traditions and revolutionary movements at the time of Jesus - provide significant background information to the Gospels. Others reflect recent and less familiar issues in Jesus and Gospel studies, such as divine man, ancient rhetoric and the chreiai. Contemporary concerns of general interest are discusses in articles covering such topics as healing, the demonic and the historical reliability of the Gospels. And for those entrusted with communicating the message of the Gospels, there is an extensive article on preaching from the Gospels. The Dictionary of Jesus and the Gospels presents the fruit of evangelical New Testament scholarship at the end of the twentieth century - committed to the authority of Scripture, utilising the best of critical methods, and maintaining dialog with contemporary scholarship and challenges facing the church.
From Essence bestselling author Kayla Perrin comes the compelling story of three generations of African-American women---of their deepest secrets and most cherished lies. The Grayson family is a pillar of the African-American community in New Orleans. But Sylvia Grayson, the matriarch, has deep secrets that she conceals beneath a veneer of propriety. She keeps a tight rein on her daughter, Olivia, and has the perfect life mapped out for her: go to college, join the Delta sorority, and marry the proper boy. After the town's "bad girl" is found murdered one summer day in 1975, Sylvia pulls Olivia even closer. But when Olivia's one last attempt at rebellion is subverted by her mother, Sylvia's relentlessly tight hold shatters the ties between them. Years later, Olivia's own daughter, Rachelle, is trying to make her way in the world. Olivia does not want to make the same mistakes as her mother, nor does she want her daughter to repeat the errors Olivia made out of rebellion. Meanwhile, a killer is watching from the shadows, determined to bring the secrets of the past to light. The Delta Sisters is a gripping, intimate portrait of what happens when these passionate women have to band together at last in the face of danger.
This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Lord Hideyoshi, the regent of Japan at the time, took the first step toward the control of firearms. It was a very small step, and it was not taken simply to protect feudal lords from being shot at by peasants but to get all weapons out of the hands of civilians. He said nothing about arms control. Instead, he announced that he was going to build a statue of Buddha that would make all existing statues look like midgets. It would be so enormous (the figure was about twice the scale of the Statue of Liberty), that many tons of iron would be needed just for the braces and bolts. Still more was required to erect the accompanying temple, which was to cover a piece of ground something over an eighth of a mile square. All farmers, ji-samurai, and monks were invited to contribute their swords and guns to the cause. They were, in fact, required to. -- from publisher description.
This will help us customize your experience to showcase the most relevant content to your age group
Please select from below
Login
Not registered?
Sign up
Already registered?
Success – Your message will goes here
We'd love to hear from you!
Thank you for visiting our website. Would you like to provide feedback on how we could improve your experience?
This site does not use any third party cookies with one exception — it uses cookies from Google to deliver its services and to analyze traffic.Learn More.