The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.
Originally published in 1985. This is a fascinating account of the life cycle of a minor literary genre, the boys’ school story. It discusses early nineteenth-century precursors of the school story – didactic works with such revealing titles as The Parents’ Assistant – and goes on to examine in detail the two major examples of the genre - Hughes’s Tom Brown’s School Days and Farrar’s Eric. The slow development of the genre during the 1860s and 1870s is traced, and its institutionalisation by Talbot Baines Reed in, for example, The Fifth Form at St Dominic’s, is described. Many similar works were subsequently published for adults and adolescents, and the author shows how they differ from the originals in being critical in tone and written to a formula in plot and style. This development is discussed in relation to the changing social structure of Britain up to 1945, by which time to life of the genre was almost ended.
A surprise visitor to the Aerie provides devastating news for Happenstance about his past--but it's the future that Umber and Hap must contend with: they need to learn all they can about Meddlers if they are to discover what Hap's role in Umber's mission is to be. And that means a risky trip to The Inferno, where Caspar has taken the key pages of Umber's research. But that's only one of the perilous journeys Umber has in mind for his mysterious ward: Umber's nemesis, the wheeling and dealing Hameron, has acquired some dragon eggs, and Umber can't resist the opportunity to study a new magical species, even if it means a trip to the corrupt kingdom of Sarnica. But when he and Hap see what the warlord of Sarnica has planned for the dragon hatchlings at the upcoming Dragon Games, Umber's quest for knowledge turns into a dangerous rescue operation.
As young Hap prepares to reverse the global catastrophe on Lord Umber's world, an evil prince and a destructive sorceress threaten the kingdom of Kurahaven.
Three French Hens and a Murder is Book 4 in The Charlie Kingsley Cozy Novella series by USA Today bestselling author Michele PW (Pariza Wacek). Ideal for cozy mystery fans, especially readers who love clean, twisty and funny cozy mysteries that include tea, pets, baking, small towns and quirky side characters. “This was a really neat mystery. … Great little story.” Ruth McDaniel “This was a fun, quick, Christmas mystery—well, as much fun as a murder can be.” Sue Ellen Three French hens, two elves, and one Santa Claus make for merry mayhem for Charlie Kingsley and the gang. When Charlie and Pat see an injured Santa on the side of the road in the middle of a snowstorm, of course they had to stop and take him to the hospital. They assumed that would be the end of their good Samaritan duties, until a dead elf is discovered in the same area where they picked up Santa … and Santa has no memory of what happened. With Santa being the number one suspect, Charlie and Pat race to discover what really happened and keep Christmas from being cancelled. Meet Charlie. Better known as "Aunt Charlie" from the award-winning Secrets of Redemption series. She's back, making teas and solving cases in this funny, twisty, cozy mystery series set in the 1990s in Redemption, Wisconsin.
Master storyteller P.W. Catanese begins the Books of Umber trilogy with Happenstance Found—now available in paperback—when twelve-yearold Happenstance awakens in a cave with no memory of who he is or how he came to be there. Lord Umber and his companions rescue Hap, and the group sets out on dangerous and unusual missions that continue in Dragon Games. Hap’s and Umber’s journeys take them to the corrupt kingdom of Sarnica, where Umber’s nemesis has acquired some dragon eggs. Umber wants to study a new magical species, but what starts as a quest for knowledge turns into a dangerous rescue operation. The deft plotting of these actionpacked, heart-stopping adventures will pique the imagination and leave readers anxious for the final installment.
Fifty thousand years in the future the universe begins to collapse prematurely. Despite having advanced technology the only viable options to survive the end of the universe come down to creating a Dyson Sphere enclosed in shielding that would resist the collapsing forces during the progression towards singularity and investigating a mysterious object that has been sighted two billion light years away towards the edge of the universe. Because of its bizarre nature this enigmatic vessel is rumored to have come from a prior universe. While the Dyson is being built and populated, Mila and Thorne are sent on what is considered a long shot expedition to see if the rumors are true; if this strange object is really from a prior universe, could it guide them to the next? On a planet where the infrastructure is failing, Strider and his mysterious telepathic companion known only as The Sylk struggle to survive in the hope of finding answers to questions they can barely even understand yet. As all these paths converge can humanity forge a path beyond the end of this universe; can they find a way forward to a new future?
Finch has written a blood-soaked historical epic to rank with the best' Anthony Riches, author of Storm of War The throne of England is under threat, but one lad’s battle is much closer to home. Storm clouds gathering at England’s shores... Autumn, 1066. Saxon England, a realm at peace for fifty years, unknowingly enjoys its last peaceful harvest. For a Viking horde, led by the dreaded Harald Hardraada, circles off the north-eastern coast, while William of Normandy, a wolf in human guise, waits in the south, greedily sizing up the wealthy kingdom. ...will change a young man’s future... Seventeen-year-old Cerdic, as second in line to the earldom of Ripon in northern England, is being trained for a future in the Church. But croziers and catechism do not fire Cerdic’s soul. He longs instead to be a warrior, like his brother Unferth, and ride to battle in defence of his lands. ...and unseat his whole world But as the invasion fleets sail, Cerdic finds himself caught in a maelstrom that will utterly reshape the life he used to know. A catastrophic war is coming to England, and Cerdic’s wish for battle looks set to come true... Sunday Times bestselling author Paul Finch’s first historical novel is an edge-of-your-seat coming-of-age adventure in early medieval England, perfect for fans of David Gilman and Bernard Cornwell. Praise for Usurper 'Usurper is an action-packed, coming-of-age, adventure set against the upheaval and battles of 1066. Finch gives us Cerdic, a troubled hero thrown into the maelstrom of events outside of his control, and we follow him breathlessly as he deals with brutal Vikings, familial rivalries, unrequited love, invading Normans and more!' Matthew Harffy, author of the Bernicia Chronicles '*Usurper *propels the reader from the very first page through a dark and desperate age when Britons fought for their survival. Fearsome battles, believable characters, uncommon valour. A relentless page turner' David Gilman, author of the Master of War series 'The grim world of Anglo Saxon England is brought evocatively to life by master storyteller Paul Finch as he thrusts the reader deep into the cold and mud and blood of a country teetering on the brink of a devastating war for survival. Usurper is a must-read for any lover of history, capturing all the rich detail of a turbulent time and stitching it through with powerful emotion' James Wilde, author of the Hereward Chronicles 'An authentic and vivid depiction of life in England in 1066, and a brutal, blood-soaked thriller that will be loved by fans of Cornwell's Last Kingdom' Alex Gough, author of the Imperial Assassins series 'Finch brings 1066 to life in new and vivid ways. Packed with blistering battle scenes and believable characters, this is a superb historical novel' Steven A. McKay, author of the Druid series
The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.
The Organic Chemistry of Nickel, Volume II: Organic Synthesis describes the chemistry of the organonickel complexes and the use of nickel in organic synthesis. Composed of six chapters, this volume starts with discussions on the oligomerization, co-oligomerization, and polymerization of olefins, followed by short accounts of the mechanistically related isomerization and hydrogenation of olefins, as well as the hydrosilylation and hydrocyanation reactions. Chapter II examines the oligomerization of acetylene and substituted alkynes, the co-oligomerization of alkynes with olefins, the related oligomerization of allene, including a number of telomerization reactions involving alkynes or allenes. Chapters III and IV describe the oligomerization, co-oligomerization, and polymerization of butadiene and substituted 1,3-dienes. Chapter V explores the coupling of organic halides in the presence of stoichiometric amounts of zerovalent nickel complexes, and the nickel-catalyzed cross-coupling reaction between organic halides and Grignard reagents. Lastly, Chapter VI emphasizes the carbonylation of alkynes, olefins, and organic halides using nickel complexes. This book will be of great value to organic chemists and researchers who are interested in the application of nickel complexes to organic synthesis.
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