Oleg V. Krylov's Books

Adsorption and Catalysis on Transition Metals and Their Oxides

By: Vsevolod F. Kiselev,Oleg V. Krylov

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Adsorption and Catalysis on Transition Metals and Their Oxides

By: Vsevolod F. Kiselev,Oleg V. Krylov

This book deals with adsorption and catalysis on the surface of transition elements and their compounds, many of which are in teresting because of their particular electronic structure. The authors have worked through a vast body of experimental evi dence on the structure and properties of surfaces of transition metals and relevant oxides. Consideration is given mostly to simple (as opposed to mixed) oxides of transition elements, to common metals and to the adsorption of simple gases. A great deal of attention is paid to the nature of active surface sites responsible for chemisorption and catalytic transformations. The description relies mainly on the simplified ligand-field theory, which, however, proves quite satisfactory for predicting the adsorptive and catalytic activity of species. In many cases simple systems were explored with the aid of novel techniques, and it is only for such systems that the mechanism of the ele mentary act of adsorption and catalysis can be given adequate treatment. The present monograph has emerged from our earlier work in Russian, which appeared in the Khimiya Publishing House (Mos cow) in 1981. This English edition has, however, been revised completely to broaden its scope and to include more recent a chievements. For fruitful discussions the authors are grateful to A.A.

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Page Count

453

Publisher

Springer Science & Business Media

Published Date

ISBN 10

3642738877

ISBN 13

9783642738876

Nonequilibrium Processes in Catalysis

By: Oleg V. Krylov

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Nonequilibrium Processes in Catalysis

By: Oleg V. Krylov

Nonequilibrium Processes in Catalysis presents modern ideas and experimental data (e.g., molecular beams, laser technique) on adsorption and catalysis, the mechanism of energy exchange in the processes of particles interaction with a surface, and the lifetimes of excited particles on a surface. Previously unpublished theoretical information regarding the principle of chemoenergetical stimulation accounting for the acceleration of one reaction at the expense of reactant excitation in another is provided, and new ideas about nonequilibrium surface diffusion are explored. Examples of the formation of nonequilibrium dissipative structures in catalysis are presented, including auto-oscillations, auto-waves, multiplicity of kinetic regimes, nonequilibrium phase transition, and decelerated electron exchange between solid and adsorbed species. The book also describes new experimental methods for studying nonequilibrium and quick processes in catalysis. Nonequilibrium Processes in Catalysis will benefit physicists involved with surface science, chemists involved with adsorption and catalysis, engineers, vacuum scientists, physical chemists, materials chemists, students, and others interested in these processes.

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Page Count

312

Publisher

CRC Press

Published Date

ISBN 10

1351083473

ISBN 13

9781351083478

Catalysis by Nonmetals

Rules for Catalyst Selection

By: Oleg V. Krylov

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Catalysis by Nonmetals

Rules for Catalyst Selection

By: Oleg V. Krylov

Catalysis by Non-metals: Rules of Catalyst Selection presents the development of scientific principles for the collection of catalysts. It discusses the investigation of the mechanism of chemosorption and catalysis. It addresses a series of properties of solid with catalytic activity. Some of the topics covered in the book are the properties of a solid and catalytic activity in oxidation-reduction reactions; the difference of electronegativities and the effective charges of atoms; the role of d-electrons in the catalytic properties of a solid; the color of solids; and proton-acid and proton-base properties of a surface. The catalytic activity and structure of solids are covered. The type of crystal lattice and crystalline lattice parameters are discussed. The text describes the decomposition of alcohols. A study of the dehydrogenation and hydrogenation reactions is presented. A chapter is devoted to the decomposition of inorganic hydrides. Another section focuses on the hydrogen-deuterium exchange and other simple reactions. The book can provide useful information to scientists, physicists, students, and researchers.

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Page Count

296

Publisher

Academic Press

Published Date

ISBN 10

1483191753

ISBN 13

9781483191751

Book's by Oleg V. Krylov

Adsorption and Catalysis on Transition Metals and Their Oxides

Adsorption and Catalysis on Transition Metals and Their Oxides

Nonequilibrium Processes in Catalysis

Nonequilibrium Processes in Catalysis

Catalysis by Nonmetals

Catalysis by Nonmetals

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