Alloys of Uranium with Alkali Metals, Alkaline Earths, and Elements of Main Groups III and IV. The description of uranium and its compounds, for which the Gmelin Institute has started a series of volumes supplementing the main volume of 1936, follows in its arrangement closely the order chosen for the transuranium volumes. Part A treats "The Element", Part B "The Metal and its Alloys", Part C "The Compounds", Part D "The Chemistry in Solution", and finally Part E "The Coordination Compounds". Part E, "The Coordination Compounds" comprises two volumes which already have been finished and are available - completely written in English. Series A comprises 7 volumes which are all available. Series C will comprise 14 volumes of which only volume 6 is missing. Series D consists of 4 volumes dealing with the chemistry in solution, which already have been finished and are available. The present volume describes the alloys and the intermetallic compounds with the metals of main groups I to IV - those systems with semimetals such as boron and germanium are to be found in corresponding volumes in Uranium C series. In the volume B 2 main emphasis is given to the binary systems. The most frequently investigated systems are uranium-beryllium and uranium-aluminium because of their special scientific (U-Be) and technological (U-Al) importance.
The volume covers alloys and intermetallic compounds of thorium with metals of main groups I to IV as well as related ternary and quaternary alloys. It is the first comprehensive and critical treatise on this topic. The physical properties of ThBe13 have been studied in some detail in order to compare them with those of the heavy fermion compound UBe13. The Th-MG system is of interest for the metallurgy of Mg, since small amounts of Th improve the mechanical strength of Mg and some of its alloys. Detailed information is available on the Th-AI system which is complicated by several intermediate binary phases. Several years ago, this system had attained some technological interest when Th-AI alloys were considered as a potential fuel in thorium breeder reactors. Other Th-main group intermetallic systems are more of scientific than of technological interest. The phase relations in these systems were not elucidated until the 1980s. Numerous ternary alloys consisting of thorium, a metal of main groups I to IV, and a third metal are described. Recent interest has focused on some ternary compounds related to the Th-AI and Th-Sn systems, e.g., THAI8Fe4 and ThSnM (M = Ni, Co, Pt).
Alloys of Uranium with Alkali Metals, Alkaline Earths, and Elements of Main Groups III and IV. The description of uranium and its compounds, for which the Gmelin Institute has started a series of volumes supplementing the main volume of 1936, follows in its arrangement closely the order chosen for the transuranium volumes. Part A treats "The Element", Part B "The Metal and its Alloys", Part C "The Compounds", Part D "The Chemistry in Solution", and finally Part E "The Coordination Compounds". Part E, "The Coordination Compounds" comprises two volumes which already have been finished and are available - completely written in English. Series A comprises 7 volumes which are all available. Series C will comprise 14 volumes of which only volume 6 is missing. Series D consists of 4 volumes dealing with the chemistry in solution, which already have been finished and are available. The present volume describes the alloys and the intermetallic compounds with the metals of main groups I to IV - those systems with semimetals such as boron and germanium are to be found in corresponding volumes in Uranium C series. In the volume B 2 main emphasis is given to the binary systems. The most frequently investigated systems are uranium-beryllium and uranium-aluminium because of their special scientific (U-Be) and technological (U-Al) importance.
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