Crystal engineers aim to control the way molecules aggregate in the crystalline phase and are therefore concerned with crystal structure prediction, polymorphism, and discovering the relative importance of different types of intermolecular forces and their influence on molecular structure. In order to design crystal structures, knowledge of the types, strengths, and nature of possible intermolecular interactions is essential. Non-covalent interactions involving p-systems is a theme that is under extensive investigation as these interactions can be inductors for the assembly of a vast array of supramolecular architectures. The Importance of Pi-Interactions in Crystal Engineeringcovers topics ranging from the identification of interactions involving p-systems, their impact on molecular and crystal structure in both organic and metallorganic systems, and how these interactions might be exploited in the design of new materials. Specialist reviews are written by internationally recognized researchers drawn from both academia and industry. The Importance of Pi-Interactions in Crystal Engineeringprovides an essential overview of this important aspect of crystal engineering for both entrants to the field as well as established practitioners, and for those working in crystallography, medicinal and pharmaceutical sciences, solid-state chemistry, physical chemistry, materials and nanotechnology
In 1944 Lady Park Wood (45 hectares of woodland in Gloucestershire and Monmouthshire, UK) was set aside indefinitely by the Forestry Commission so that ecologists could study how woodland develops naturally. Since then, in a unique long-term study, individual trees and shrubs have been recorded at intervals, accumulating a detailed record of more than 20,000 individual beech, sessile oak, ash, wych elm, small-leaved lime, large-leaved lime, birch, hazel, yew and other species. In the seven decades since the study started, the wood has changed; trees grew, died and regenerated, and drought, disease and other events shaped its destiny. Each tree and shrub species reacted in its own way to changes in the wood as a whole and to changes in the fortunes of its neighbours. Meanwhile, the wild fauna, flora and fungi also responded, leaving the wood richer in some groups but poorer in others. In this landmark book, beautifully illustrated throughout, George Peterken and Edward Mountford, summarise the ongoing results of the Lady Park Wood study, highlighting its unique place in nature conservation and its significance to ecology in general. It also builds on experience at Lady Park Wood and elsewhere to discuss in particular: the role and maintenance of long-term ecological studies; the concept and form of natural woodland; the role of minimum-intervention policies in woodland nature conservation; near-to-nature forestry; and the desirability and practicalities of re-wilding woodlands.
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