Equilibrium Constants of Liquid-Liquid Distribution Reactions, Part III: Compound Forming Extractants, Solvating Solvents, and Inert Solvents focuses on the compilation of equilibrium constants of various compounds, such as acids, ions, salts, and aqueous solutions. The manuscript presents tables that show the distribution reactions of carboxylic and sulfonic acid extractants and their dimerization and other reactions in the organic phase and extraction reactions of metal ions from aqueous solutions. The book also states that the inorganic anions in these solutions are irrelevant, since they do not take part in the extraction reaction. The publication examines tables that illustrate the distribution of inorganic acids, salts, and complexes between aqueous solutions and solvents that have oxygen donor atoms. Tables that show the distribution of inorganic acids, salts, and complexes between aqueous solutions and inert solvents that do not have donor atoms and often utilized as inert diluents are also presented. The manuscript is a vital reference for readers and researchers interested in the equilibrium constants of compounds.
Equilibrium Constants of Liquid-liquid Distribution Reactions Introduction, and Part 1: Organophosphorus Extractants focuses on the numerical representations, formulas, reactions, and characteristics of equilibrium constants of organophosphorus extractants. The text underscores that only a number of papers focusing on equilibrium constants for distribution reactions involving metal complexes are published before 1947. The book also states that no equilibrium constants have been reported on several organophosphorus extractants although they are used in practical extraction work. The publication provides a list of extractants, ligands, and metal ions. These include distribution and dissociation of extractants; dimerization and aggregation of extractants; homogeneous equilibria of extractants with metal ions; extraction of metal ions with extractants as ligands; and reactions of extractants with diluents and other solvents. The manuscript also highlights reactions, temperature, and equilibrium constants. The book is a valuable source of data for readers interested in the equilibrium constants of organophosphorus extractants.
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