Claudia Heinrich-Sterzel's Books

N Nitrogen

By: Reinhard Haubold,Peter Merlet,Claudia Heinrich-Sterzel,Astrid Wietelmann,Ulrike Ohms-Bredeman,Carol Strametz

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N Nitrogen

By: Reinhard Haubold,Peter Merlet,Claudia Heinrich-Sterzel,Astrid Wietelmann,Ulrike Ohms-Bredeman,Carol Strametz

This volume deals with binary nitrogen-hydrogen compounds having two, three, or more nitrogen atoms (with the exception of hydrazine) and with compounds composed of nitrogen, hydrogen, and noble gases. The important species containing two nitrogen atoms, N2H, N2H+, N2H2, and N2H3 are described in the first part of this volume. Next, chains and cycles consisting of three nitrogen atoms are covered. Among them hydrogen azide or hydrozoic acid, HN3, is the most extensively studied nitrogen-hydrogen compound described in this volume. With increasing number of nitrogen atoms, the thermochmical stability declines. There is, however, a considerable amount of information on molecules with up to nine linked nitrogen atoms. Several of these binary nitrogen-hydrogen compounds could only be isolated in the form of organic derivatives. In that case, data available for the organic derivatives were included if they were characteristic for the particular unsubstituted N-H parent compound.

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Page Count

202

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Springer Science & Business Media

Published Date

ISBN 10

3662063360

ISBN 13

9783662063361

N Nitrogen

Compounds with Noble Gases and Hydrogen

By: Walter Hack,Reinhard Haubold,Ulrike Ohms-Bredemann,Claudia Heinrich-Sterzel,Hannelore Keller-Rudek,Dag Schiöberg,Carol Strametz

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N Nitrogen

Compounds with Noble Gases and Hydrogen

By: Walter Hack,Reinhard Haubold,Ulrike Ohms-Bredemann,Claudia Heinrich-Sterzel,Hannelore Keller-Rudek,Dag Schiöberg,Carol Strametz

Nitrogen" Suppt. Vol. B 1 describes the compounds of nitrogen with noble gases and, in the major part, binary compounds composed of one nitrogen atom and hydrogen. Nitrogen hydrogen compounds with two and more nitrogen atoms are covered in "Nitrogen" Suppt. Vol. 82. There is some information on various nitrogen-noble gas species, to a large extent because of the interest in their bonding behavior. Experimental data have been obtained chiefly for some singly charged cations, particularly those formed by argon Like ArN + and ArNi. The existence of others has only been established by mass spectrometry. The binary compounds of nitrogen and hydrogen comprise NH, NH , NH , NH , the corre 2 4 5 sponding ions, and some adducts. NH and NH1 are not treated. The predominant part 3 of the volume covers the description of the molecules NH and NH . 8oth species are present 2 in photolytic processes in the atmosphere. They play an essential role in combustion systems regardless of whether the nitrogen stems from the nitrogen-containing fuel or from the air. Thus, much work has been devoted to the understanding of the nitrogen chemistry in combustion and in the atmosphere. The production and detection methods as weiL as the reactions have been comprehensively described. ln addition detailed information is given on the spectral behavior, the knowledge of which is important for detecting the mole cules and for studying their kinetics.

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292

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Springer Science & Business Media

Published Date

ISBN 10

3662063336

ISBN 13

9783662063330

Binary Species of Silicon and Fluorine

By: Friedrich Schröder,Edwin Hengge,Robert Schlögl,Claudia Heinrich-Sterzel,Peter Merlet,Jörn v. Jouanne,Hans Schäfer,Alfred Pebler,Sigrid Ruprecht,Dag Schiöberg,Joachim Wagner

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Binary Species of Silicon and Fluorine

By: Friedrich Schröder,Edwin Hengge,Robert Schlögl,Claudia Heinrich-Sterzel,Peter Merlet,Jörn v. Jouanne,Hans Schäfer,Alfred Pebler,Sigrid Ruprecht,Dag Schiöberg,Joachim Wagner

The volume is concerned exclusively with all the binary species formed between the elements silicon and fluorine such as SiF, SiF2, SiF3, SiF4, and Sif62-. Most of the volume, i.e. 144 pages, is devoted to the description of the well known physical and chemical properties of the SiF4 as well as to its preparation. This is followed in length by the report on SiF2 with its interesting chemistry, along with a section on the diatomic radical SiF. Species with fivefold and sixfold coordination of silicon are exemplified by SiF5- and by the well known SiF62-. Interestingly, the detailed models for describing the bonding situation in both ions are still a matter of discussion. While for Si2F6 most of the basic data are known, information on the chemical and physical properties of the higher members of the acylic perfluorosilanes, SinF2n+2, is scarce. All available information on the unstable cyclic perfluorosilanes of composition (SiF2)n and some even more exotic species is also included.

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Page Count

376

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Springer

Published Date

ISBN 10

3540936513

ISBN 13

9783540936510

Book's by Claudia Heinrich-Sterzel

N Nitrogen

N Nitrogen

N Nitrogen

N Nitrogen

Binary Species of Silicon and Fluorine

Binary Species of Silicon and Fluorine

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