The aim of this book is to explore the detectable properties of a material to the parameters of bond and non-bond involved and to clarify the interdependence of various properties. This book is composed of four parts; Part I deals with the formation and relaxation dynamics of bond and non-bond during chemisorptions with uncovering of the correlation among the chemical bond, energy band and surface potential barrier (3B) during reactions; Part II is focused on the relaxation of bonds between atoms with fewer neighbors than the ideal in bulk with unraveling of the bond order-length-strength (BOLS) correlation mechanism, which clarifies the nature difference between nanostructures and bulk of the same substance; Part III deals with the relaxation dynamics of bond under heating and compressing with revealing of rules on the temperature-resolved elastic and plastic properties of low-dimensional materials; Part IV is focused on the asymmetric relaxation dynamics of the hydrogen bond (O:H-O) and the anomalous behavior of water and ice under cooling, compressing and clustering. The target audience for this book includes scientists, engineers and practitioners in the area of surface science and nanoscience.
This book features the latest advances and future trends in water science and technology. It also discusses the scientific popularization and quantitative resolution of a variety of mysterious properties of water and ice from the perspective of hydrogen-bond cooperativity in response to stimuli such as chemical contamination, electrification, magnetification, mechanical compression, molecular undercoordination, and thermal excitation. Anomalies include the floating of ice, the Hofmeister effect in solutions, regelation of ice, slipperiness of ice, water’s tough skin, the Mpemba paradox, and the floating bridge. It also addresses the superfluidity of microchannels, hydrogen bond potentials, nanodroplet and bubble thermodynamics, quasisolidity and supersolidity, controlling superhydrophobicity–superhydrophilicity transition, and high-pressure ice formation. The target audience for this book includes students, senior scholars, engineers and practitioners in the area of physical chemistry, biology, as well as aqueous and colloid solutions.
Polysaccharide nanocrystals, an emerging green nanoingredient (nanomaterial) with high crystallinity obtained by acid hydrolysis of biomass-based polysaccharides, are of scientific and economic significance owing to their abundance, biodegradation potential, and fascinating functional performance. This versatile class of materials can be used in nanocomposites such as rubber or polyester, and in functional materials such as drug carriers, bio-inspired mechanically adaptive materials or membranes, to name but a few. This book encompasses the extraction, structure, properties, surface modification, theory, and mechanism of diverse functional systems derived from polysaccharide nanocrystals. This highly sought-after trendy book is currently the only monograph devoted to the most current knowledge pertaining to this exciting subject area. It is ideal for researchers and stakeholders who wish to broaden and deepen their knowledge in the fast-moving and rapidly expanding R&D field of polymeric materials.
This book highlights the latest advances and outlines future trends in aqueous solvation studies from the perspective of hydrogen bond transition by charge injection, which reconciles the solvation dynamics, molecular nonbond interactions, and the extraordinary functionalities of various solutes on the solution bond network and properties. Focus is given on ionic and dipolar electrostatic polarization, O:H nonbond interaction, anti-HB and super-HB repulsion, and solute-solute interactions. Its target audience includes researchers, scientists, and engineers in chemistry, physics, surface and interface science, materials science and engineering.
This book provides a comprehensive overview of the fundamental properties, preparation routes and applications of a novel class of organic–inorganic nanocomposites known as periodic mesoporous organosilicas (PMOs). Mesoporous silicas are amorphous inorganic materials which have silicon and oxygen atoms in their framework with pore size ranging from 2 to 50 nm. They can be synthesized from surfactants as templates for the polycondensation of various silicon sources such as tetraalkoxysilane. In general, mesoporous silica materials possess high surface areas, tunable pore diameters, high pore volumes and well uniformly organized porosity. The stable chemical property and the variable ability for chemical modification makes them ideal for many applications such as drug carrier, sensor, separation, catalyst, and adsorbent. Among such mesoporous silicas, in 1999, three groups in Canada, Germany, and Japan independently developed a novel class of organic–inorganic nanocomposites known as periodic mesoporous organosilicas (PMOs). The organic functional groups in the frameworks of these solids allow tuning of their surface properties and modification of the bulk properties of the material. The book discusses the properties of PMOs, their preparation, different functionalities and morphology, before going on to applications in fields such as catalysis, drug delivery, sensing, optics, electronic devices, environmental applications (gas sensing and gas adsorption), biomolecule adsorption and chromatography. The book provides fundamental understanding of PMOs and their advanced applications for general materials chemists and is an excellent guide to these promising novel materials for graduate students majoring in chemical engineering, chemistry, polymer science and materials science and engineering.
This book presents the latest advances and future trends in electron and phonon spectrometrics, focusing on combined techniques using electron emissions, electron diffraction, and phonon absorption and reflection spectrometrics from a substance under various perturbations to obtain new information on bond-electron-phonon dynamics. Discussing the principles of the bond order-length-strength (BOLS) correlation, nonbonding electron polarization (NEP), local bond average (LBA), and multi-field lattice oscillation dynamics for systems under perturbation, the book covers topics like differential photoelectron/phonon spectrometrics (DPS), which distils transition of the length, energy, stiffness and the fraction of bonds upon chemical or physical conditioning; and the derived performance of electrons in various bands in terms of quantum entrapment and polarization. This book appeals to researchers, scientists and engineers in the fields of chemistry, physics, surface and interface science, and materials science and engineering who are interested in electron and phonon spectrometrics.
Energy efficiency issues for green internet of things (IoT) are investigated in this book, from the perspectives of device-to-device (D2D) communications, machine-to-machine (M2M) communications, and air-ground networks. Specifically, critical green IoT techniques from D2D communications in the cellular network to M2M communications in industrial IoT (IIoT), (from single physical-layer optimization to cross-layer optimization, and from single-layer ground networks to stereoscopic air-ground networks) are discussed in both theoretical problem formulation and simulation result analysis in this book. Internet of Things (IoT) offers a platform that enables sensors and devices to connect seamlessly in an intelligent environment, thus providing intelligence services including monitoring systems, industrial automation, and ultimately smart cities. However, the huge potentials of IoT are constrained by high energy consumption, limited battery capacity, and the slow progress of battery technology. The high energy consumption of IoT device causes communication interruption, information loss, and short network lifetime. Moreover, once deployed, the batteries inside IoT devices cannot be replaced in time. Therefore, energy efficient resource allocation is urgent to be investigated to improve the energy efficiency of IoT, facilitate green IoT, and extend the network lifetime. This book provides readers with a comprehensive overview of the state-of-the-art key technologies, frameworks, related optimization algorithms, and corresponding integrated designs on green IoT. It also presents an easy-to-understand style in a professional manner, making the book suitable for a wider range of readers from students to professionals interested in the green IoT.
Presents novel, nanotechnology-based solutions for urgent environmental engineering problems Clear and concise from beginning to end, this book focuses on the design and application of artificially intelligent nanomaterials, which help in solving many tangible environmental problems?especially water and air pollution. It lays out the design concepts, major chemical principles, and materials considerations of artificially intelligent nanomaterials for environmental engineering, and provides proof-of-concept examples such as improved filtration membranes, nanofibrous air filters, and molecularly imprinted nanomaterials. Artificially Intelligent Nanomaterials: For Environmental Engineering starts by describing the background of environmental nanotechnology, the rise of Artificial Intelligence (AI), and the current status of AI in environmental engineering. It then looks at: intelligently functional materials and responsive mechanisms; designing filtration membranes with responsive gates; switchable wettability materials for controllable oil/water separation; and self-healing materials for environmental applications. The book continues with chapters that examine: emerging nanofibrous air filters for PM2.5 removal; self-propelled nanomotors for environmental applications; molecular imprinting in wastewater treatment; and emerging synergistically multifunctional and all-in-one nanomaterials and nanodevices in advanced environmental applications. -Presents the state-of-the-art in environmental technology and puts forward bold ideas for its advancement -Addresses global challenges, including all important water and air quality which are critical for human health and a sustainable future -Concentrates on nanotechnology-enabled solutions for pollutant removal from water and air Artificially Intelligent Nanomaterials: For Environmental Engineering is an ideal book for undergraduates, graduates, scientists, and professionals in the fields of environmental science, material science, chemistry, and chemistry engineering.
Power systems worldwide are going through a paradigm shift from centralized generation to distributed generation. This book presents the SYNDEM (i.e., synchronized and democratized) grid architecture and its technical routes to harmonize the integration of renewable energy sources, electric vehicles, storage systems, and flexible loads, with the synchronization mechanism of synchronous machines, to enable autonomous operation of power systems, and to promote energy freedom. This is a game changer for the grid. It is the sort of breakthrough — like the touch screen in smart phones — that helps to push an industry from one era to the next, as reported by Keith Schneider, a New York Times correspondent since 1982. This book contains an introductory chapter and additional 24 chapters in five parts: Theoretical Framework, First-Generation VSM (virtual synchronous machines), Second-Generation VSM, Third-Generation VSM, and Case Studies. Most of the chapters include experimental results. As the first book of its kind for power electronics-enabled autonomous power systems, it • introduces a holistic architecture applicable to both large and small power systems, including aircraft power systems, ship power systems, microgrids, and supergrids • provides latest research to address the unprecedented challenges faced by power systems and to enhance grid stability, reliability, security, resiliency, and sustainability • demonstrates how future power systems achieve harmonious interaction, prevent local faults from cascading into wide-area blackouts, and operate autonomously with minimized cyber-attacks • highlights the significance of the SYNDEM concept for power systems and beyond Power Electronics-Enabled Autonomous Power Systems is an excellent book for researchers, engineers, and students involved in energy and power systems, electrical and control engineering, and power electronics. The SYNDEM theoretical framework chapter is also suitable for policy makers, legislators, entrepreneurs, commissioners of utility commissions, energy and environmental agency staff, utility personnel, investors, consultants, and attorneys.
Prostate cancer is the second leading cause of death in men and its progression is highly dependent on androgens and androgen receptors. However, even with treatment, eventually most prostate cancers progress. Studies of the mechanisms behind this progression leads to advances in treatments for androgen-related diseases. Our book discusses recent prostate cancer research, which includes the following topics: immunotherapy and chemotherapy; radiation, gene, hormonal, and androgen ablation therapies; basic mechanisms behind prostate cancer growth; how mechanisms can be used to treat prostate cancer; and research in newly developed mouse model systems.This book should be of interest as both a study guide and research reference to students, basic scientists, and clinicians.
Musculoskeletal applications of tissue engineering will be among the first to achieve widespread clinical use, and the resulting shift in clinical and surgical paradigms will highlight the need for an authoritative text on tissue engineering for musculoskeletal tissues including nerve, bone, tendon, skin, vessels, and cartilage. This book will serve the needs of a large readership including plastic surgeons, orthopedic surgeons, medical residents and medical students, researchers and academic faculty in regenerative medicine and biomedical engineering, and medical device experts. This textbook will serve as the curriculum for undergraduate and graduate courses in biomedical engineering and surgery. Notable contributors to this volume include Antonios G Mikos, PhD; Wei Liu, MD; Yilin Cao, MD; Mark Randolph, MAS; Jennifer Elisseeff, PhD; Geoffrey C Gurtner, MD; Michael T Longaker, MD; and James Chang, MD, all of whom are leaders in tissue engineering research and applications.
Microbial Biodegradation of Xenobiotic Compounds examines and collects the recent information on the bioremediation technologies around the world. This book focuses on methods to decrease pollutants created by anthropogenic activities, industrial activities, and agricultural activities. This book answers some of the questions about – how to reduce contaminants? And whether there is a possibility of converting these pollutants in to useful energy by advanced biotechnological methods? The book combines present obtainable data with the expert knowledge of researchers from all over the world covering different aspects of environmental biotechnology and microbiology. It covers basic concepts of bioremediation and various methods involved in the bioremediation process, and provides specific chapters on the role of different genes and enzymes involved in microbial bioremediation process. It also gives special attention to heavy metal bioremediation by microalgae and the mechanisms involved during the degradation process. Recent innovative technologies about converting toxic pollutants in to useful energy like bioplastics and electricity are also discussed by specialist authors. Various chapters address the bioremediation of pesticides in soil using microbial metabolites, and molecular aspects of biodegradation which cover topics including identification of novel genes through the metagenomic approach and bioremediation using fungal laccase enzymes.
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