Ali Morsali's Books

Pillared Metal-Organic Frameworks

Properties and Applications

By: Lida Hashemi,Ali Morsali

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Pillared Metal-Organic Frameworks

Properties and Applications

By: Lida Hashemi,Ali Morsali

In the last two decades, metal-organic frameworks (MOFs) have provoked considerable interest due to their potential applications in different fields such as catalysis, gas storage and sensing. The most important advantages of MOFs over other porous materials is the ability of tailoring their pore size, functionality and even the topology of the framework by rational selection of the molecular building blocks. Therefore, many chemists have tried to engineer the structure of MOFs to achieve specific functions. Pillared metal organic frameworks are a class of MOFs composed of inorganic secondary building units (SBUs) and two sets of organic linkers, generally oxygen- and nitrogen-donor ligands. Typically, in the structure of pillared MOFs, the oxygen-donor struts link the metal clusters into a two-dimensional (2D) sheet and the N-donor struts pillar the sheets to generate a three-dimensional (3D) framework. Thus, the construction of MOFs by utilizing two sets of organic linkers could provide an extra possibility for further tuning of MOF’s pore walls. A variety of functional groups including imine, amide and heterocycles were successfully incorporated into bidentate pillar ligand skeleton. Interestingly, by using pillaring linkers with different length, a wide diversity of metal-organic frameworks with tunable pore dimensions and topologies can be obtained. In this book, we introduce pillared metal organic frameworks with their properties and applications.

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Page Count

230

Publisher

John Wiley & Sons

Published Date

ISBN 10

1119460379

ISBN 13

9781119460374

Functional Metal-Organic Frameworks

Structure, Properties and Applications

By: Ali Morsali,Sayed Ali Akbar Razavi

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Functional Metal-Organic Frameworks

Structure, Properties and Applications

By: Ali Morsali,Sayed Ali Akbar Razavi

Owing to the extensive interest in construction of functional metal organic frameworks (FMOFs), this book discusses the roles of functional groups on the structure and application of metal organic frameworks (MOFs). The contents of the book are classified based on the structural and chemical properties of organic functions, in order to make readers able to compare the different effects of each function on the structure and application of the MOFs. In each chapter, the chemical properties of applied functional groups are gathered to give deeper insight into the roles of organic functions in the structure and application of MOFs. In the function-application properties, the authors discuss how a functional group can dominate the host-guest chemistry of the MOFs and how this host-guest chemistry can expand the effectiveness and efficiency of the material in different fields of applications. Finally, function-structure properties are discussed. In function-application properties, it is discussed how a functional group can affect the topology, porosity, flexibility and stability of the framework. The features of this subject are novel and are presented for the first time.

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Page Count

256

Publisher

John Wiley & Sons

Published Date

ISBN 10

1119640431

ISBN 13

9781119640431

Two-Dimensional Nanostructures

By: Mahmood Aliofkhazraei,Nasar Ali

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Two-Dimensional Nanostructures

By: Mahmood Aliofkhazraei,Nasar Ali

After the 2010 Nobel Prize in Physics was awarded to Andre Geim and Konstantin Novoselov "for groundbreaking experiments regarding the two-dimensional material graphene," even more research and development efforts have been focused on two-dimensional nanostructures. Illustrating the importance of this area in future applications, Two-Dimensional Nanostructures covers the fabrication methods and properties of these materials. The authors begin with discussions on the properties, size effect, applications, classification groups, and growth of nanostructures. They then describe various characterization and fabrication methods, such as spectrometry, low-energy electron diffraction, physical and chemical vapor deposition, and molecular beam epitaxy. The remainder of the text focuses on mechanical, chemical, and physical properties and fabrication methods, including a new mechanical method for fabricating graphene layers and a model for relating the features and structures of nanostructured thin films. With companies already demonstrating the capabilities of graphene in a flexible touch-screen and a 150 GHz transistor, nanostructures are on their way to replacing silicon as the materials of choice in electronics and other areas. This book aids you in understanding the current chemical, mechanical, and physical processes for producing these "miracle materials.

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Page Count

325

Publisher

CRC Press

Published Date

ISBN 10

1439866651

ISBN 13

9781439866658

Pillared Metal-Organic Frameworks

Properties and Applications

By: Lida Hashemi,Ali Morsali

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Pillared Metal-Organic Frameworks

Properties and Applications

By: Lida Hashemi,Ali Morsali

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Page Count

382

Publisher

John Wiley & Sons

Published Date

ISBN 10

1119460395

ISBN 13

9781119460398

Main Group Metal Coordination Polymers

Structures and Nanostructures

By: Ali Morsali,Lida Hashemi

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Main Group Metal Coordination Polymers

Structures and Nanostructures

By: Ali Morsali,Lida Hashemi

Coordination polymer is a general term used to indicate an infinite array composed of metal ions which are bridged by certain ligands among them. This incorporates a wide range of architectures including simple one-dimensional chains with small ligands to large mesoporous frameworks. Generally, the formation process proceeds automatically and, therefore, is called a self-assembly process. In general, the type and topology of the product generated from the self-assembly of inorganic metal nodes and organic spacers depend on the functionality of the ligand and valences and the geometric needs of the metal ions used. In this book the authors explain main group metal coordination polymer in bulk and nano size with some of their application, synthesis method and etc, The properties of these efficient materials are described at length including magnetism (long-range ordering, spin crossover), porosity (gas storage, ion and guest exchange), non-linear optical activity, chiral networks, reactive networks, heterogeneous catalysis, luminescence, multifunctional materials and other properties.

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Page Count

262

Publisher

John Wiley & Sons

Published Date

ISBN 10

1119370752

ISBN 13

9781119370758

Book's by Ali Morsali

Pillared Metal-Organic Frameworks

Pillared Metal-Organic Frameworks

Functional Metal-Organic Frameworks

Functional Metal-Organic Frameworks

Two-Dimensional Nanostructures

Two-Dimensional Nanostructures

Pillared Metal-Organic Frameworks

Pillared Metal-Organic Frameworks

Main Group Metal Coordination Polymers

Main Group Metal Coordination Polymers

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