Volume 7B Selected papers from the Seventh National Meeting of the Society for Applied Spectroscopy (Nineteenth Annual Mid-America Spectroscopy Symposium) Held in Chicago, Illinois, May 13–17, 1968
Volume 7B Selected papers from the Seventh National Meeting of the Society for Applied Spectroscopy (Nineteenth Annual Mid-America Spectroscopy Symposium) Held in Chicago, Illinois, May 13–17, 1968
Volume 7 of Developments in Applied Spectroscopy is a collection of forty-two papers selected from those that were presented at the 7th National Meeting of the Society of Applied Spectroscopy, held (in place of the 19th Mid-America Symposium on Spectroscopy) in Chicago, May 13-17, 1968. These papers, selected by the editors and reviewed by persons knowledgeable in the field, are those of the symposium type and not those pertaining to specific research topics that one would expect to be submitted to a journal. It is the opinion of the committee that this type of publication has an important place in the literature. The relatively large number of papers would result in quite a sizable volume if bound in one set of covers. For this reason, and to present the material in areas of more specific iilterest, Volume 7 was divided into two parts, Part A, Physical-Inorganic, and Part B, Physical-Organic Developments. The 7th National Meeting was sponsored by the Chicago Section as host in cooperation with the St. Louis, New England, Penn York, Niagara-Frontier, Cincinnati, Ohio Valley, New York, Baltimore-Washington, North Texas, Rocky Mountain, and Southeastern Sections of the Society for Applied Spectroscopy and the Chicago Gas Chromatography Group. The editors wish to express their appreciation to the authors and to those who helped with the reviewing. The latter include Dr. Elma Lanterman, Mr. John E. Forrette, Dr. Carl Moore, Dr. B. Jaselskis, Mr. H. G. Zelinski, Mr.
Volume 6 of Developments in Applied Spectroscopy presents a collection of twenty-eight selected papers from those that were pre sented at the Eighteenth Mid-America Symposium on Spectroscopy held in Chicago, May 15 to 18, 1967. In general, the papers selected by the editors are those of the symposium type and not those papers pertaining to a specific research topic that one expects to be sub mitted to a journal. Not all of the submitted papers were included. Some revisions could not meet the deadline and others were not accepted based on the advice of the reviewers. It is the opinion of the committee that this type of publication has ·an important place in the literature. The Mid-America Symposium is sponsored annually by the Chicago Section in cooperation with the Cincinnati, Detroit, Indianapolis, Milwaukee, Niagara Frontier, and St. Louis Sections of the Society of Applied Spectroscopy, and the Chicago Gas Chromatography Group. Although the Mid-America is often thought of as a regional meeting, its attendees and authors generally come from all parts of the United States and Canada. Both applied and theoretical principles were provided in sessions on X-ray, emission, atomic-absorption, nuclear magnetic resonance, infrared, Raman, nuclear-particle, and gamma ray spectroscopy; activation analysis; and gas chromatography. In addition, there were symposia on absorption spectra of biologically significant molecules; the structure of ice, water, and aqueous solu tions; air and water pollution analyses; and the practical application of statistics.
This book is intended both to be an introduction to techniques and applications of liquid chromatography/mass spectrometry and to serve as a reference for future workers. When we undertook its writing, we chose not to cover the field, particularly applications, exhaustively. Rather we wished to produce a book that would be of use to people just beginning to use the technique as well as to more advanced practitioners. In this regard, we have sought to highlight techniques and applications that are of current importance, while not neglecting descriptions of approaches that may be of significance in the future. We hope that we have succeeded in this. At the same time we hope that the bibliography, with indexes classified by author and title, will make this book of value to those who may disagree with our emphasis. ACKNOWLEDGMENTS. One of us (C. G. E. ) wishes to acknowledge the en couragment of Professor J. A. McCloskey in undertaking this project. All four of us are grateful for the continuous and expert assistance of V. A. Edmonds in the preparation of the Bibliography. Alfred L. Y ergey Bethesda, Maryland Charles G. Edmonds Richland, Washington lvor A. S. Lewis London, England Marvin L. Vestal Houston, Texas v Contents 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . 1 . . . . . . . . . . . 2. Direct Liquid Introduction Interfaces . . . . . . . . . . 5 . . . 2. 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2. 2. Operating Principles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2. 3. Specific DLI Interfaces . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2. 3. 1. Capillary Inlets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2. 3. 2. Diaphragm Interfaces . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 2. 3. 3. Nebulizing Interfaces . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
The role of large-scale business enterprise—big business and its managers—during the formative years of modern capitalism (from the 1850s until the 1920s) is delineated in this pathmarking book. Alfred Chandler, Jr., the distinguished business historian, sets forth the reasons for the dominance of big business in American transportation, communications, and the central sectors of production and distribution. The managerial revolution, presented here with force and conviction, is the story of how the visible hand of management replaced what Adam Smith called the “invisible hand” of market forces. Chandler shows that the fundamental shift toward managers running large enterprises exerted a far greater influence in determining size and concentration in American industry than other factors so often cited as critical: the quality of entrepreneurship, the availability of capital, or public policy.
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