High-Pressure Chemistry and Physics of Polymers is devoted to covering all areas of high-pressure polymer materials science. Topics addressed include the synthesis of polymers, changes in reactivity, structural transformations, molecular dynamics, relaxation processes, deformational properties, chemical modification, and the effect of shock waves and shear stresses. The authors' contributions reflect over 60 years of Soviet study in the field of physico-chemistry conducted at the major former Soviet Institutes of Chemical Physics, Organic Chemistry, Polymer Chemistry, and Physical Chemistry. Fundamental topics such as compressibility of polymers, polymerization under pressure, viscoelastic/deformational properties, and polymer modification are discussed with an eye toward materials development for improving physical models and methods of calculating the changing parameters of materials under pressure. The book is a valuable reference to data on mechanisms of physical and chemical processes, in addition to new experimental data for improving physical models and methods of calculating changes in material characteristics under compression loads. High-Pressure Chemistry and Physics of Polymers will be an important reference for graduate students and practicing professionals in polymer chemistry and polymeric materials.
This volume focuses on the dynamical behaviour of low-molecular additives in solid polymer matrixes. It covers: types and models of molecular motion in condensed media; dependence of motional frequency on particle structure and size, temperature, volume and stress; and polymer properties and polymeric structures. Extensive analysis of common regularities of rotational and translational dynamics of molecules introduced into polymers are given. The book also includes experimental techniques for molecular mobility evaluation, and features detailed data on rotational dynamics of additives. It should be of interest to specialists in various fields of polymer physical chemistry and materials science.
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